Browsing Magister Scientiae - MSc (Chemistry) by Title
Now showing items 11-30 of 177
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Carbon supported aluminium trifluoride nanoparticles functionalized lithium manganese oxide for the development of advanced lithium ion battery system
(University of the Western Cape, 2017)A novel lithium ion (Li-ion) battery cathode material has been investigated for potential mobile technology energy storage applications. I have successfully synthesized Lithium Manganese oxide (LMO), reduced Graphene Oxide ... -
Carbon-carbon coupling reactions catalysed by palladium nanoparticles supported on the green alga Ulva armoricana
(University of Western Cape, 2018)The synthesis of nanomaterials, especially metallic nanoparticles, has attracted an enormous amount of interest over the past decade. They exhibit unique properties that allow the multiple applications in a variety of ... -
Catalyst Coated Membranes (CCMs) for polymerelectrolyte Membrane (PEM) fuel cells
(University of the Western Cape, 2010)The main objective of this work it to produce membrane electrode assemblies (MEAs) that have improved performance over MEAs produced by the conventional manner, by producing highly efficient, electroactive, uniform catalyst ... -
Cation-exchanged zeolites-A prepared from South African fly ash feedstock for CO2 adsorption
(University of the Western Cape, 2015)In South Africa coal combustion constitutes up to 90 % of the country’s energy need. This coal combustion activity is known to contribute to the amount of about 40 % of the total CO2 atmospheric emissions worldwide that ... -
Cesium hydrogen sulphate and cesium dihydrogen phosphate based solid composite electrolyte for fuel cell application
(University of the Western Cape, 2004)A new high temperature solid electrolyte composite was developed, with CsHSO4 and CsH2PO4 as the proton conducting material in composition with PTFE and SiO2 to enhance the solid electrolyte composites mechanical strength ... -
Characterization and chemical speciation modelling of saline effluents at Sasol Synthetic Fuels Complex-Secunda and Tukuta power station
(University of the Western Cape, 2009)The study shows conclusively that brine composition and concentration is highly variable at these South African power utilities and processes such as RO, contact with ash and CO2 ingress can have an impact upon the overall ... -
Characterization of platinum-group metal nanophase electrocatalysts employed in the direct methanol fuel cell and solid-polymer electrolyte electrolyser
(University of the Western Cape, 2005)Characterization of nanophase electrocatalysts, which are an essential part in the direct methanol fuel cell (DMFC) and solid-polymer electrolyte (SPE) electrolyser, have been studied in this work. Their nanoparticulate ... -
Charge Transfer and Capacitive Properties of Polyaniline/ Polyamide Thin Films
(University of the Western Cape, 2018)Blending polymers together offers researchers the ability to create novel materials that have a combination of desired properties of the individual polymers for a variety of functions as well as improving specific properties. ... -
Chemical and biological evaluation of palythoa tuberculosa collected from the red sea
(University of the Western Cape, 2015)A chemical study on the total extract of the zoanthid Palythoa tuberculosa, collected from the Red Sea, resulted in the isolation of seven polyhydroxylated sterols viz: palysterols A-G, six of which are new. Their chemical ... -
Chemical studies on some natural products from Myrothamnus flabellifolius
(University of the Western Cape, 2014)Crude extracts from Myrothamnus flabellifolius were fractionated through variouschromatography techniques in order to achieve satisfactory separations. Two compounds, arbutin and lupeol, were isolated from ... -
Chemical, physical and morphological changes in weathered brine slurried coal fly ash
(University of the Western Cape, 2011)Energy production from coal comes with an environmental cost because of the toxic waste produced during coal combustion such as coal ash and brine which are potential water and soil pollutants. Coal ash and brine contain ... -
Chemical, physical and morphological changes in weathered coal fly ash : a case study of brine impacted wet ash dump
(University of the Western Cape, 2011)Fly ash is the major waste material produced by power plants in the combustion of coal to generate electricity. The main constituents of fly ash are Si, Al, Fe and Ca with smaller amount of S, Mn, Na, K, and traces of ... -
CO2 sequestration using brine impacted fly fish
(University of the Western Cape, 2009)It was hypothesized that South African FA and brine could sequester CO2 through mineral carbonation. A statistical approach was undertaken to optimize the % CaCO3 formed from FA/brine/CO2 interaction with input parameters ... -
Composite low temperate hydrogen storage material on the basis of iron-titanium alloy ; synthesis and structure
(University of the Western Cape, 2006)It is widely believed that hydrogen will within a few tens of years become the means of storing and transporting energy. The reason is the depletion of hydrocarbons and the relatively facile production of hydrogen from ... -
The composition of photocatalytic nanofibres through electrospinning
(University of the Western Cape, 2014)The aim of this study was to enrich electrospun fibres with the active mineral phase TiO2 nanoparticles and then to evaluate how well the composite fibres performed in the photocatalytic degradation of methylene blue ... -
Consolidated nanomaterials synthesized using nickel micro-wires and carbon nanotubes
(University of the Western Cape, 2007)Nano-devices are the next step in the application of nanomaterials in modern technology. One area of research that is receiving an increased amount of attention globally is the fabrication of new nano-devices for applications ... -
Construction of an enzyme-free electrochemical sensor based on Ag-Fe2O3/POM/RGO novel nanocomposite for hydrogen peroxide detection
(University of the Western Cape, 2018)The motivation to determine H2O2 lies in the fact that this chemical species plays a crucial role in diverse fields of practise such as cosmetic, food, diagnostic, pharmaceutical, clinical and environmental protection ... -
Coordination polymers as heterogeneous catalysts for oxidation reactions
(University of the Western Cape, 2014)This study describes the synthesis and characterisation of coordination polymers complexes of Cu(II) and VO(IV) with two polymeric ligands N,Nʹ -1,2-phenylene bis(5-methylenesalicylidenamine)(L1) and N,Nʹ -1,4-butylene ... -
Cytochrome C biosensor for the determination of trace level arsenic and cyanide compounds
(University of the Western Cape, 2011)In this work, an electrochemical method based on a cyt c biosensor has been developed, for the detection of selected arsenic and cyanide compounds. Boron Doped Diamond (BDD) electrode was used as a transducer, onto which ... -
Cytochrome P450 2E1/Nickel-Poly(propylene imine) dendrimeric nanobiosensor for pyrazinamide - A first line TB Drug
(University of the Western Cape, 2015)The tuberculosis (TB) disease to this day remains one of the world’s prominent killerdiseases. Pyrazinamide (PZA) is one of the most commonly prescribed anti- tuberculosis (anti-TB) drugs due to its ability to significantly ...