Browsing Department of Chemistry by Title
Now showing items 345-364 of 399
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Synthesis and characterization of new adsorbents for CO2 capturing
(University of the Western Cape, 2014)Carbon dioxide emissions have become a major concern as they are one of the contributing factors to the “green-house” effect. Recently, much effort has been put into separating carbon dioxide (CO2) from flue gases linked ... -
Synthesis and characterization of pt-sn/c cathode catalysts via polyol reduction method for use in direct methanol fuel cell
(2013)Direct methanol fuel cells (DMFCs) are attractive power sources as they offer high conversion efficiencies with low or no pollution. One of the major advantages DMFCs has over PEMFCs is that methanol is a liquid and can ... -
Synthesis and characterization of pyridyl/quinolyl imine ruthenium(II) and palladium (II) complexes in catalysis
(University of the Western Cape, 2015)We report the successful syntheses of a family of tetradentate N-donor pyridyl and quinolyl-imine ligands N1,N2-bis((pyridin-2-yl)methylene)ethane-1,2-diamine (L1), N1,N3- bis(pyridin-2-ylmethylene)propane-1,3-diamine (L2), ... -
Synthesis and characterization of rhenium (vii) and rhuthenium (ii) dendritic catalysts: oxidative cleavage and epoxidation of alkenes
(2012)Herein we report the successful synthesis of a class of stable and flexible Schiff-base chelators capable of coordinating both ruthenium (II) and rhenium (VII) and which would be catalytically active for oxo-transfer ... -
Synthesis and characterization of zinc-doped magnetic nanoparticles for diagnostic studies
(University of the Western Cape, 2015)In the present study we report the synthesis and characterization of iron oxide magnetic nanoparticles doped with zinc in an attempt to enhance the magnetic properties. The nanoparticles were prepared via the co-precipitation ... -
Synthesis and characterizations of nanostructured MnO2 electrodes for supercapacitors applications
(University of the Western Cape, 2010)The objective of this research was to develop highly efficient and yet effective MnO2 electrode materials for supercapacitors applications. Most attention had focussed on MnO2 as a candidate for pseudo-capacitor, due to ... -
Synthesis and electrochemical characterisation of conducting polyaniline-fly ash matrix composites
(2005)The aim of this study was to produce useful composite materials from fly ash, a major waste product of coal combustion from power plants. Polyaniline-fly ash (PANI-FA) composites were prepared by in situ polymerisation of ... -
Synthesis and electrochemical modulation of the actuator properties of poly(phenazine-2,3-diimino (pyrrol-2-yl))
(University of the Western Cape, 2008)The focus of this study is to synthesize a novel hinged polymer actuator. The linking molecule (hinge) is phenazine with interconnected dipyrrole units. -
The synthesis and electrochemical studies of chalcones and flavanones: an investigation of their antioxidant activity
(University of Western Cape, 2013)Flavonoids, one of the biggest classes of secondary metabolites, are found abundantly in nature in a broad range of fruits, vegetables and beverages such as tea, coffee, beer, wine and fruit drinks. Flavonoids have been ... -
Synthesis and electrochemistry of novel conducting dendrimeric star copolymers on poly(propylene imine) dendrimer
(University of the Western Cape, 2011)One of the most powerful aspects of conducting polymers is their ability to be nanostructured through innovative, synthetically manipulated, transformations, such as to tailor-make the polymers for specialized applications. ... -
Synthesis and evaluation of metformin derivatives for anti-diabetes
(University of the Western Cape, 2022)Type 2 diabetes mellitus (T2DM) is a significant public health crisis and is placed amongst the top ten leading causes of death worldwide. Metformin is the first-line drug used to treat T2DM, which is mainly attributed to ... -
The synthesis and evaluation of potential anti-Mycobacterium tuberculosis and apoptotic agents
(University of the Western Cape, 2007)Tuberculosis (TB) and Cancer are among the most devastating and therapeutically challenging diseases that need to be addressed in South Africa today. The development of muti-drug resistance in TB causing bacteria, Mycobacterium ... -
Synthesis and Luminescence of Zinc Oxide Nanorods-Blended Thiopheno-Organosilicon Polymers
(University of the Western Cape, 2017)The increasing cost of fossil fuel energy production and its implication in environmental pollution and climate change created high demand for alternative and renewable sources of energy. This has led to great interest ... -
Synthesis and properties of nanoparticulate titanium dioxide compounds
(University of the Western Cape, 2009)An electrolytic cell was designed and constructed for the preparation of TiO2 nanotubes. Conditions of anodic oxidation were established to reproducibly prepare TiO2 nanotubes of average length 35-50 μm vertically orientated ... -
The synthesis of 3-allyl-4-ethyl-2- (1'-hydroxyethyl)-1-methoxynaphthalene and its behaviour towards base- and palladium-promoted cyclisation under aerobic and anaerobic conditions
(University of the Western Cape, 2005)Over the years, Giles and co-workers have established that, upon treatment with potassium tert-butoxide, tetra-substituted naphthalenes undergo cyclisations to afford naphthopyrans. It was suggested that these base-induced ... -
The synthesis of analogues of the Anti-TB (agent: Diospyrin)
(University of the Western Cape, 2005)Diospyrin, a bisnaphthyl quinone molecule with proven anti-TB activity can be retrosynthetically formulated into two halves. In this work, the analogue chosen to be synthesized was similarly retrosynthesized into two halves. ... -
The Synthesis of Biaxial Naphthoquinones and an Initial Investigation regarding their Potential as anti- Mycobacterium tuberculosis and Apoptotic Agents
(University of the Western Cape, 2009)Tuberculosis and cancer are amongst the most devastating diseases affecting the world today, especially Africa and other less developed countries. Both diseases have the ability to develop resistance against drugs being ... -
Synthesis of binary and ternary Pd-based Nanocatalysts for alcohol oxidation in alkaline media for fuel cell application
(University of the Western Cape, 2020)This study explores the use of UV-assisted reduction method to synthesise the catalysts, aiming at reducing synthesis time. The Pd and Au catalyst loading is kept at 5 wt% in order to reduce the cost associated with high ... -
Synthesis of DMSO based silver nanoparticles for application in wound healing
(University of Western Cape, 2021)Silver nanoparticles (AgNPs) apart from being chemically significant, have shown a lot of health benefits, the most studied being their anti-bacterial and anti-inflammatory properties. These biological properties can be ... -
Synthesis of metal modified Mesoporous Zeolites catalysts: application in conversion of Olefins to Valuable liquid products
(University of the Western Cape, 2016)The effects of temperature, synthesis duration and silica source were studied to obtain suitable conditions for our laboratory experiment concerned with the synthesis of MCM-41 catalyst. The transformation of 1-hexene was ...