Browsing Philosophiae Doctor - PhD (Chemistry) by Title
Now showing items 25-44 of 133
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The development of graphene oxide sheet- and polyanilino-immunosensor systems for lipoarabinomannan (LAM) tuberculosis biomarker
(University of the Western Cape, 2017)Tuberculosis (TB) is an infectious disease with adverse effect on a global scale. The disease is one of the major causes of death in sub-Saharan Africa. Nearly 70% of TB-infected persons are co-infected by the human ... -
Development of heterostructured tin oxide nanocatalysts for the synthesis of bio-based maleic acid
(University of Western Cape, 2021)Maleic acid (MA) is a key intermediate for the synthesis of polyester resins, surface coatings, lubricant additives, plasticizers, copolymers, pharmaceuticals and agricultural chemicals. The current industrial production ... -
Development of high performance composite lithium ion battery cathode systems with carbon nanotubes functionalised with bimetallic inorganic nanocrystal alloys
(University of Western Cape, 2011)Lithium ion cathode systems based on composites of lithium iron phosphate (LiFePO₄), iron-cobalt-derivatised carbon nanotubes (FeCo-CNT) and polyaniline (PA) nanomaterials were developed. The FeCo-functionalised CNTs were ... -
Development of Impedimetric Immunosensor for Fumonisin on Polyanilino-Carbon Nanotubes Doped with Palladium Telluride Nanocrystals
(University of the Western Cape, 2013)Immunosensors are affinity ligand-based biosensor solid-state devices in which the immunochemical reaction is coupled to a transducer. The specificity of the molecular recognition of antigens by antibodies to form a stable ... -
The development of inorganic and organic/inorganic membranes for DMFC application
(University of the Western Cape, 2004)A fuel cell is an energy device that converts chemical energy to electrical energy. Low temperature fuel cells, namely the hydrogen fuel cell and the direct methanol fuel cell are preferred amongst other fuel cell types ... -
Development of Metal Nanoparticle-Doped Polyanilino-Graphene Oxide High Performance Supercapacitor Cells
(University of the Western Cape, 2018)Supercapacitors, also known as ultracapacitors or electrochemical capacitors, are considered one of the most important subjects concerning electricity or energy storage which has proven to be problematic for South Africa. ... -
Development of nanostructured electrocatalysts using electrochemical atomic layer deposition technique for the direct liquid fuel cells By
(University of Western Cape, 2020)The depletion of fossil fuel resources such as coal and the concern of climatic change arising from the emission of greenhouse gases (GHG) and global warming [1] lead to the identification of the 'hydrogen economy' as one ... -
Development of new dendritic ligands for copper mediated Atom Transfer Radical Polymerization (ATRP) of methyl methacrylate
(University of the Western Cape, 2007)A variety of nitrogen based dendritic ligands have been synthesized and used in copper mediated Atom Transfer Radical Polymerization (ATRP) of MMA. These ligands were derived from the commercially available Generation 1 ... -
Development of platino-iridium/ruthenium telluride nanoalloy electrode systems for possible application in ammonia fuel cell
(University of the Western Cape, 2015)South Africa is undergoing a serious consideration of hydrogen economy in an effort to develop safe clean and reliable alternative energy sources for fossil fuels. Ammonia is one of the promising candidates due to its low ... -
Development of polyaniline nanotube electrocatalysts and sesor devices for phenolic-pollutants
(University of the Western Cape, 2007)As a source of life, water is one of the most precious commodities for all living organisms. Water resources are reported to be declining in numbers or the amount of water present and the existing onses are being polluted ... -
Development of Schiff base electrochemical sensors for the evaluation of polycyclic aromatic hydrocarbons in aqueous medium
(University of the Western Cape, 2017)A novel monomer (N,N'-Bis-(1H-pyrrol-2-ylmethylene)-benzene-1,2-diamine-BPPD) was derived from the condensation reaction between o-phenylenediamine and a pyrrole derivative. The monomer was polymerized electrochemically ... -
The effect of flow field design on the degradation mechanisms and long term stability of HT-PEM fuel cell
(University of the Western Cape, 2018)Fuel cells are long term solution for global energy needs. In current fuel cell technologies, Proton Exchange Membrane (PEM) fuel cells are known for quick start-up and ease of operation compared to other types of fuel ... -
Effluent water treatment utilising a combination of hydrodynamic shear and flotation technology for the specific application of wastewater from the oil and gas industry
(University of the Western Cape, 2022)Water plays an important role in the petrochemical production and refining processes. The wastewaters released by these processes are often rich in petroleum pollutants, that requires significant treatment prior to ... -
Electro-analytical protocols for quantitative assessment of phenols in South African rooibos, green and black tea samples
(University of Western Cape, 2022)The worldwide tea market was estimated at almost 200 billion U.S. dollars in 2020. It is perceived to rise to 318 billion dollars by 2025. Tea has a long history of prominence around the world. Increases in tea production ... -
Electrochemical and optical modulation of selenide and telluride ternary alloy quantum dots genosensors
(University of the Western Cape, 2012)Electroanalytical and optical properties of nanoscale materials are very important for biosensing applications as well as for understanding the unique one-dimensional carrier transport mechanism. One-dimensional semiconductor ... -
Electrochemical cytochrome P450 enzymatic biosensors for the determination of the reactivity of TB drugs
(University of Western Cape, 2020)Tuberculosis (TB) remains a global epidemic despite the fact that treatment has been available since the 1950’s. This disease is highly contagious and spreads via transmission of the Mycobacterium Tuberculosis (MTB) tubercle ... -
Electrochemical dynamics of cytochrome P450-3A4 isoenzyme biosensor for protease inhibitor antiretroviral drug
(2010)This thesis firstly reports on the development and characterization of reagent-less and cobalt(III) sepulchrate[Co(Sep)³⁺] mediated biosensor platforms (biosensor platform 1 and biosensor platform 2), with human recombinant ... -
Electrochemical energy conversion using metal hydrides hydrogen storage materials
(University of the Western Cape, 2010)Metal hydrides hydrogen storage materials have the ability to reversibly absorb and release large amounts of hydrogen at low temperature and pressure. In this study, metal hydride materials employed as negative electrodes ... -
Electrochemical impedance modelling of the reactivities of dendrimeric poly(propylene imine) DNA nanobiosensors
(University of the Western Cape, 2008)In this thesis, I present the electrochemical studies of three dendrimeric polypropylene imine (PPI) nanomaterials and their applications as a platform in the development of a novel label free DNA nanobiosensor based on ... -
Electrochemical ochratoxin a immunosensors based on polyaniline nanocomposites templated with amine- and sulphate-functionalised polystyrene latex beads
(University of the Western Cape, 2010)Polyaniline nanocomposites doped with poly(vinylsulphonate) (PV-SO3) and nanostructured polystyrene (PSNP) latex beads functionalized with amine (PSNP-NH2) and sulphate ((PSNP-OSO3) were prepared and characterised for use ...