Browsing Magister Scientiae - MSc (Chemistry) by Issue Date
Now showing items 21-40 of 268
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Solid phase micro extraction: an alternative technique for the determination of volatile orgnanic compounds in groundwater
(University of the Western Cape, 2004)Standard methods for sample preparation use toxic organic solvents and can be replaced by utilizing a new sample preparation and concentration technique. One such technique, compatible with capillary gas chromatography was ... -
Pyramlyl palladium(Il) complexes as phenylacetylene oligomerization and polymerization catalysts'
(University of the Western Cape, 2004)PyrazoM compounds have been extensively used to prepare metal complexes, but it is only recently that they have been investigated as catalysts for the polymerization of unsaturated hydrocarbons. In catalyzn11g the ... -
Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization
(University of the Western Cape, 2005)The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene. -
Synthesis and characterisation of proton conducting membranes for direct methanol fuel cell (DMFC) applications
(University of the Western Cape, 2005)For a direct methanol fuel cell (DMFC), the proton exchange membrane must conduct protons and be a good methanol barrier. In addition to the high methanol permeability achieved by these membranes, they are very expensive ... -
Synthesis and electrochemical characterisation of conducting polyaniline-fly ash matrix composites
(2005)The aim of this study was to produce useful composite materials from fly ash, a major waste product of coal combustion from power plants. Polyaniline-fly ash (PANI-FA) composites were prepared by in situ polymerisation of ... -
Studies on some biologically active natural products from Tulbaghia Alliacea
(University of the Western Cape, 2005)It is believed that early humans had knowledge of how to use traditional medicinal plants, but the knowledge has been partially lost as society underwent various changes leading to new civilizations. The aim of this study ... -
Fabrication and kinetic modeling of cytochrome P4502D6 amperometric biosensors for serotonin reuptake inhibitors
(University of the Western Cape, 2005)An amperometric biosensor was prepared by in situ deposition of cytochrome P4502D6 (CYP2D6, P4502D6) enzyme on a polyaniline (PANI)-doped glassy carbon electrode. The PANI film was electrochemically deposited on the electrode ... -
The application of high capacity ion exchange absorbent material, synthesized from fly ash and acid mine drainage, for the removal of heavy and trace metals from secondary co-disposed process waters
(University of the Western Cape, 2005)The objective of this study was to investigate the feasibility of the application of low cost high capacity inorganic ion exchange material, synthesized form collected fly ash and acid mine drainage solid residues, for the ... -
Polymer/nano-organic composite proton exchange membranes for direct methanol fuel cell application
(University of the Western Cape, 2005)The proton exchange membrane is one key component of direct methanol fuel cells, which has double functions of conducting protons, separating fuels and oxidant. At present, the performance and price of sulfonic acid proton ... -
Characterization of platinum-group metal nanophase electrocatalysts employed in the direct methanol fuel cell and solid-polymer electrolyte electrolyser
(University of the Western Cape, 2005)Characterization of nanophase electrocatalysts, which are an essential part in the direct methanol fuel cell (DMFC) and solid-polymer electrolyte (SPE) electrolyser, have been studied in this work. Their nanoparticulate ... -
The synthesis of 3-allyl-4-ethyl-2- (1'-hydroxyethyl)-1-methoxynaphthalene and its behaviour towards base- and palladium-promoted cyclisation under aerobic and anaerobic conditions
(University of the Western Cape, 2005)Over the years, Giles and co-workers have established that, upon treatment with potassium tert-butoxide, tetra-substituted naphthalenes undergo cyclisations to afford naphthopyrans. It was suggested that these base-induced ... -
The development of appropriate brine electrolysers for disinfection of rural water supplies
(University of the Western Cape, 2005)A comparative study of electrolysers using different anodic materials for the electrolysis of brine (sodium chloride) for the production of sodium hypochlorite as a source of available chlorine for disinfection of rural ... -
The synthesis of analogues of the Anti-TB (agent: Diospyrin)
(University of the Western Cape, 2005)Diospyrin, a bisnaphthyl quinone molecule with proven anti-TB activity can be retrosynthetically formulated into two halves. In this work, the analogue chosen to be synthesized was similarly retrosynthesized into two halves. ... -
The Development of Appropriate Brine Electrolysers for Disinfection of Rural water supplies
(University of the Western Cape, 2005)A comparative study of electrolysers using different anodic materials for the electrolysis of brine (sodium chloride) for the production of sodium hypochlorite as a source of A comparative study of electrolysers using ... -
Hydrogen selective properties of cesium-hydrogensulphate membranes
(University of the Western Cape, 2006)The production procedure of a CsHS04-Si02 composite membrane was optimized in order to obtain the highest possible H2:C02 and H2:C~ Idea selectivity permeance. The optimized membrane preparation procedure led to the ... -
Homogeneity of nanophase electrocatalysts supported on mesoporous materials
(University of the Western Cape, 2006) -
Phytochemical studies of Helichrysum patulum
(University of the Western Cape, 2006)Since Helichrysum is known by the indigenous people of Africa for therapeutic properties, such as against colds, flu and wounds, the aim of this study was to focus on the patulum species found predominantly in the Western ... -
The electrogeneration of hydroxyl radicals for water disinfection
(University of the Western Cape, 2006)This study has shown that OHË radicals can be generated in an Fe/O2 cell from the electrode products via Fenton’s reaction and used for water disinfection. The cell system in which the experiments were carried out ... -
Hydrogen selective properties of cesium-hydrogensulphate membranes
(University of the Western Cape, 2006)Over the past 40 years, research pertaining to membrane technology has lead to the development of a wide range of applications including beverage production, water purification and the separation of dairy products. For the ... -
Composite low temperate hydrogen storage material on the basis of iron-titanium alloy ; synthesis and structure
(University of the Western Cape, 2006)It is widely believed that hydrogen will within a few tens of years become the means of storing and transporting energy. The reason is the depletion of hydrocarbons and the relatively facile production of hydrogen from ...