Browsing Magister Scientiae - MSc (Chemistry) by Title
Now showing items 180-199 of 266
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Platinum based catalysts for the cathode of proton exchange membrane fuel cells
(University of the Western Cape, 2018)Oxygen reduction reaction (ORR) is carried out in the cathode of the proton exchange membrane fuel cell (PEMFC) and it is known for its sluggish kinetics and the existence of two-pathway mechanism, related with the production ... -
Polyacrylic acid and polyvinylpyrrolidone stabilised ternary nanoalloys of platinum group metals for the electrochemical production of hydrogen from ammonia
(University of the Western Cape, 2016)The electrochemical oxidation of ammonia has attracted much attention as an efficient green method for application in direct ammonia fuel cells (DAFCs) and the production of high purity hydrogen. However, the insufficient ... -
Polyamic acid-graphene oxide nanocomposite for electrochemical screening of antibiotic residues in water
(University of the Western Cape, 2015)Pollution of water sources, aquifers and wetland systems caused by industry, agriculture, and municipally treated wastewater is a worldwide problem that contributes to the scarcity of clean and potable water. Rivers, ... -
Polyanilino-graphene oxide intercalated with platinum group metal nanocomposites, for application as novel supercapacitor materials
(University of the Western Cape, 2014)Supercapacitors are one of the important subjects concerning energy storage which has proven to be a challenge in this country. Currently, the electrodes of most commercial supercapacitor are made of carbon which is known ... -
Polydopamine coated platinum catalysts to improve fuel cells durability
(University of Western Cape, 2022)Polymer electrolyte membrane fuel cells (PEMFC) are in the forefront of energy production and have drawn a great deal of attention in both fundamental and application in recent years. It is a promising energy system used ... -
Polymer/nano-organic composite proton exchange membranes for direct methanol fuel cell application
(University of the Western Cape, 2005)The proton exchange membrane is one key component of direct methanol fuel cells, which has double functions of conducting protons, separating fuels and oxidant. At present, the performance and price of sulfonic acid proton ... -
Polymeric tyrosinase nanobiosensor system for the determination of endocrine disrupting bisphenol A
(University of the Western Cape, 2011)The main objective of this work was to develop simple and sensitive electrochemical sensors for the detection of bisphenol A. To investigate the electrochemical behavior of BPA on a bare glassy carbon electrode. To apply ... -
Polyphenolic, tannin and chemical compositional changes in leaves of sub-tropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations
(University of the Western Cape, 2002)The effects of elevated atmospheric CO2 concentrations on plant polyphenolic concentration, tannin concentration and chemical composition were investigated in leaves of sub-tropical grass species and fynbos shrubs. The ... -
Polyphenolic, tannin and chemical compositional changes in leaves of sub-tropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations
(University of the Western Cape, 2002)The effects of elevated atmospheric CO2 concentrations on plant polyphenolic concentration, tannin concentration and chemical composition were investigated in leaves of sub-tropical grass species and fynbos shrubs. The ... -
Polypyrrole supports for direct alcohol fuel cells.
(University of Western Cape, 2021)Anode catalysts are one of the key components of direct alcohol fuel cells (DAFCs). They play a huge role in the alcohol oxidation reaction (AOR) that occurs on the anode side. Palladium (Pd) supported on carbon material ... -
Porous metal complexes for CO2 capturing
(University of the Western Cape, 2017)The need in energy has resulted in the burning of fossil fuels at an increasingly high level. The consequence is a release of high volumes of carbon dioxide gas (CO2) in the atmosphere. This gas is a major greenhouse gas ... -
Preliminary investigation of the natural contamination of agricultural crops with selected mycotoxins in northern rural South Africa (Limpopo and Mpumalanga Provinces)
(University of Western Cape, 2013)Subsistence farmers may contribute significantly to food production, food security, and employment in South Africa. However poor storage practices and contamination with mycotoxins, particularly fumonisins and aflatoxins ... -
Preparation and electrospinning of chitosan from waste Black Soldier Fly biomass
(University of the Western Cape, 2018)Black soldier flies are important in sustainability because of their ability to voraciously degrade organic waste without constituting a nuisance to the environment. In South Africa, Agriprotein Ltd, a company producing ... -
The preparation of an immunosensor for the detection of microcystins and nodularins by immobilisation of a labelled antibody onto a polymer modified electrode
(University of the Western Cape, 2011)South African dams and reservoirs are increasingly showing the propensity to support sustained populations of Cyanobacteria (blue green algae). These photosynthetic bacteria occur throughout the world and can rapidly form ... -
The preparation of binuclear and polynuclear methyl complexes of palladium as catalyst precursors in phenylacetylene polymerization
(University of the Western Cape, 2007)This study focused on the development of binuclear and multinuclear catalyst for use in vinylic monomer oligomerization and polymerization. The main objective was to develop new homogeneous catalysts systems with hopefully ... -
Production and evaluation of a TiO2 based 68Ge/68Ga generator
(University of the Western Cape, 2014)68Ge/68Ga generators rely on metal oxide, inorganic and organic sorbents in order to prepare radionuclides useful for clinical applications. The requirements for 68Ge/68Ga generators are that the 68Ga obtained from the ... -
Pyramlyl palladium(Il) complexes as phenylacetylene oligomerization and polymerization catalysts'
(University of the Western Cape, 2004)PyrazoM compounds have been extensively used to prepare metal complexes, but it is only recently that they have been investigated as catalysts for the polymerization of unsaturated hydrocarbons. In catalyzn11g the ... -
Pyrazole and pyrazolyl palladium(II) and platinum(II) complexes: synthesis and in vitro evaluation as anticancer agents
(University of the Western Cape, 2004)The use of metallo-pharmaceuticals, such as the platinum drugs, for cancer treatment illustrates the utility of metal complexes as therapeutic agents. Platinum group metal complexes therefore offer potential as anti-tumour ... -
Pyrazolyl palladium complexes with heterocyclic carbonyl linkers as catalyst precursors for ethylene and phenylacetylene polymerization.
(University of the Western Cape, 2003)The pyrazolyl ligands 2,6-bis(3,5-r2p*azolylcarbonyl)pyridine {r : 'bu (l1), me (l2)),2,6-bis(3-methylpyrazolylcarbonyl)pyridine(l3)'2'6- bis(pyrazolylcarbonyl)pyridine (l4) and 2,5-bis(3,5-rzpyrazolylcarbonyl)thiophene { ... -
Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization
(University of the Western Cape, 2005)The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene.