Browsing Magister Scientiae - MSc (Chemistry) by Title
Now showing items 194-213 of 266
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The preparation of binuclear and polynuclear methyl complexes of palladium as catalyst precursors in phenylacetylene polymerization
(University of the Western Cape, 2007)This study focused on the development of binuclear and multinuclear catalyst for use in vinylic monomer oligomerization and polymerization. The main objective was to develop new homogeneous catalysts systems with hopefully ... -
Production and evaluation of a TiO2 based 68Ge/68Ga generator
(University of the Western Cape, 2014)68Ge/68Ga generators rely on metal oxide, inorganic and organic sorbents in order to prepare radionuclides useful for clinical applications. The requirements for 68Ge/68Ga generators are that the 68Ga obtained from the ... -
Pyramlyl palladium(Il) complexes as phenylacetylene oligomerization and polymerization catalysts'
(University of the Western Cape, 2004)PyrazoM compounds have been extensively used to prepare metal complexes, but it is only recently that they have been investigated as catalysts for the polymerization of unsaturated hydrocarbons. In catalyzn11g the ... -
Pyrazole and pyrazolyl palladium(II) and platinum(II) complexes: synthesis and in vitro evaluation as anticancer agents
(University of the Western Cape, 2004)The use of metallo-pharmaceuticals, such as the platinum drugs, for cancer treatment illustrates the utility of metal complexes as therapeutic agents. Platinum group metal complexes therefore offer potential as anti-tumour ... -
Pyrazolyl palladium complexes with heterocyclic carbonyl linkers as catalyst precursors for ethylene and phenylacetylene polymerization.
(University of the Western Cape, 2003)The pyrazolyl ligands 2,6-bis(3,5-r2p*azolylcarbonyl)pyridine {r : 'bu (l1), me (l2)),2,6-bis(3-methylpyrazolylcarbonyl)pyridine(l3)'2'6- bis(pyrazolylcarbonyl)pyridine (l4) and 2,5-bis(3,5-rzpyrazolylcarbonyl)thiophene { ... -
Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization
(University of the Western Cape, 2005)The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene. -
Recovery of SiO₂ and Al₂O₃ from coal fly ash
(University of the Western Cape, 2016)Most of the world's energy production is still mainly achieved by the combustion of coal in power stations. Coal fly ash is the inevitable waste product that accumulates to metric ton volumes each year. These vast volumes ... -
Removal of sulphates from South African mine water using coal fly ash
(University of the Western Cape, 2009)This study evaluated SO4 2- removal from circumneutral mine water (CMW) collected from Middleburg coal mine using coal FA collected from Hendrina power station. The following parameters were investigated: the effect of the ... -
Removal of sulphates from South African mine water using coal fly ash
(University of the Western Cape, 2009)South African power stations generate large amounts of highly alkaline fly ash (FA). This waste product has a serious impact on the environment. Acid mine drainage (AMD) is another environmental problem associated with ... -
The response dynamics of indium telluride quantum dots impedimetric genosensor for telomerase cancer biomarker
(2013)Cancer, the second most common cause of death after heart disease, is a complex and multifactorial disease that up to date is still under extensive research. To achieve early detection of cancer disease the discovery of ... -
The role of aluminium content in the control of the morphology of fly ash based hierarchical zeolite X
(University of the Western Cape, 2015)Coal is the main source of electricity in South Africa, the combustion of which produces a large amount of waste (coal fly ash) annually. The large-scale generation of coal fly ash places major strain on landfills and the ... -
The role of surface modified TiO2 nanoparticles for application in 68Ge/68Ga generator systems and the use of molecular imprinted polymers for 68Ge breakthrough control
(University of Western Cape, 2021)Titanium dioxide (TiO2) has potential as an adsorbent within the 68Ge/68Ga generator context. To function effectively, three basic requirements are required: optimum 68Ga elution efficiency, stability and removal of the ... -
Scalable synthesis of innovative silicon/carbon nanocomposite for next generation lithium-ion battery anodes
(University of the Western Cape, 2022)Silicon is the most promising lithium-ion battery (LIB) anode due to its ultra-high capacity (4200 mAh/g), which is 10 times greater than commercially available graphite anodes (372 mAh/g). Utilizing this large capacity ... -
Secondary metabolites of the uromycladium tepperianum macalpine epiphytic fungus
(University of the Western Cape, 2021)Research on natural products and medicinal plants has been conducted more with each passing year due to the great interest in isolating bioactive compounds and secondary metabolites from natural products such as plants, ... -
Secondary metabolites of the uromycladium tepperianum McAlpine epiphytic fungus
(University of the Western Cape, 2021)Research on natural products and medicinal plants has been conducted more with each passing year due to the great interest in isolating bioactive compounds and secondary metabolites from natural products such as plants, ... -
Silver-coated polyethene terephthalate membrane for detection of pharmaceuticals using surface-enhanced Raman spectroscopy
(University of the Western Cape, 2017)Surface-enhanced Raman spectroscopy (SERS) has emerged as one of the analytical tools for detection of micro pollutants in the aquatic environment. The SERS technique is touted to have fingerprinting capability, specificity, ... -
Solid phase micro extraction: an alternative technique for the determination of volatile orgnanic compounds in groundwater
(University of the Western Cape, 2004)Standard methods for sample preparation use toxic organic solvents and can be replaced by utilizing a new sample preparation and concentration technique. One such technique, compatible with capillary gas chromatography was ... -
Some new bimetallic nickel and palladium complexes for catalysis applications
(University of the Western Cape, 2015)This thesis reports on the syntheses of new bimetallic iminopyridyl nickel(II) and palladium(II) complexes as catalyst precursors for ethylene ligomerization/polymerization. Tetrahydrophenyl-linked iminopyridyl ligands, ... -
Sorption properties of natural zeolites for the removal of ammonium and chromium ions in aqueous solution
(University of the Western Cape, 2011)There are huge amount of natural clinoptilolite available in South Africa which can be utilised for wastewater treatment of ammonia and chromium if their characteristics are properly known. However, these deposits have not ... -
Spectroelectrochemical graphene-silver/zinc oxide nanoparticulate phenotype biosensors for ethambutol and pyrazinamide
(University of the Western Cape, 2019)Tuberculosis (TB), a deadly disease second to HIV/AIDS, is a global health problem. Diagnosis of active tuberculosis is tedious and requires expensive procedures since there is no recognizable method for sole detection ...