Browsing Philosophiae Doctor - PhD (Chemistry) by Title
Now showing items 48-67 of 133
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Evaluation of the leachate chemistry and contaminants attenuation in acid mine drainage by fly ash and its derivatives
(University of the Western Cape, 2006)The mining industry in South Africa has a huge potential to impact negatively on the environment. Negative impacts include generation of reactive tailings and acid mine drainage (AMD). AMD is highly acidic (pH 2-4), ... -
Extraction, fractionation, nanoparticles formulation, and antimicrobial activity of lipids from black soldier fly larvae
(University of Western Cape, 2021)Hermetia illucens (Diptera: Stratiomyidae) known as the black soldier fly (BSF) is an efficient ecological organic waste decomposer. Its larvae grow through six larval instars on a variety of decomposing organic substrates ... -
Fabrication of luminescent nanocomposites for diagnosis of breast cancer
(University of the Western Cape, 2016)In this study we were able to synthesize separately iron oxide magnetic nanoparticles, InP/ZnSe and CdTe/ZnS quantum dots. The iron oxide nanoparticles were coupled with InP/ZnSe QDs to form the luminescent magnetic ... -
Fabrication of metal-organic frameworks with application-specific properties for hydrogen storage application
(University of Western Cape, 2019)The application of porous materials into industrial hydrogen (H2) storage systems is based on their use in combination with high-pressure cylinders. The processing of metal-organic frameworks (MOF) powders into shaped ... -
Fabrication of nanomaterials from biomass for adsorption and antimicrobial applications
(University of the Western Cape, 2020)The Black soldier fly (BSF) is an environmentally friendly and sustainable insect utilised in the decomposition of organic waste. This is due to its voracious consumption capability, disruptive functions and economic ... -
Fabrication of type-I indium-based near-infrared emitting quantum dots for biological imaging applications
(University of the Western Cape, 2013)Semiconductor nanocrystals or quantum dots (QDs) are fluorescent nanometer-sized particles which have physical dimensions that are smaller than the excitonic Bohr radius, large surface area-to-volume ratios, broad ... -
Factors influencing fuel cell life and a method of assessment for state of health
(University of the Western Cape, 2018)Proton exchange membrane fuel cells (PEMFC) converts chemical energy from the electrochemical reaction of oxygen and hydrogen into electrical while emitting heat, oxygen depleted air (ODA) and water as by-products. The ... -
Frequency and voltage-modulated electrochemical aflatoxin B1 immunosensor systems prepared on electroactive organic polymer platforms
(University of the Western Cape, 2008)In the presented work, immunosensors for detection of Aflatoxin B1 based on different immobilization platforms were studied. Synthesis of an electroactive hydrogel was also carried out. Aflatoxins are a group of mycotoxins ... -
Frequency and voltage-modulated electrochemical aflatoxin b1immunosensor systems prepared on electroactive organic polymer platforms
(2008)In the presented work, immunosensors for detection of Aflatoxin B1 based on different immobilization platforms were studied. Synthesis of an electroactive hydrogel was also carried out. Aflatoxins are a group of mycotoxins ... -
Functionalisation of electrospun nanofibre for lanthanide ion adsorption from aqueous solution
(University of the Western Cape, 2018)Rare earth elements (REEs) have widespread use and importance for industrial applications due to their metallurgical, optical and electronic properties. Several typical hydrometallurgical techniques such as adsorption, ... -
Functionalisation of polymer nanofibres and track-etched membrane removal of organic and and inorganic pollutants from water
(University of the Western Cape, 2017)Organic and inorganic pollutants are two broad classes of pollutants in the environment with their main sources from waste waters that are indiscriminately dumped from chemical related industries. Among the organic ... -
Gas diffusion electrodes for high temperature polymer electrolyte membrane fuel cells membrane electrode assemblies
(University of the Western Cape, 2014)The need for simplified polymer electrolyte membrane fuel cell (PEMFCs) systems, which do not require extensive fuel processing, has led to increased study in the field of high temperature polymer electrolyte membrane fuel ... -
Graphenated electrode protocol for electrochemical nanosensing of 17β- estradiol as an environmental estrogeneous endocrine disruptor
(University of the Western Cape, 2016)17β-Estradiol can be defined as an endocrine disruptor chemical with estrogenic activity, which can bind to the estrogen receptor in the body and potentially alter the normal physiological function of the endocrine ... -
Graphenated polyaniline nanocomposite for the determination of polyaromatic hydrocarbons (pahs) in water
(2013)The thesis presents a simple, sensitive, low cost and a novel graphenated polyaniline doped tungsten trioxide nanocomposite, as an electrochemical sensor for the detection and quantitative and determination of PAHs, which ... -
Graphol and vanadia-linkedzink-doped lithium manganese silicate nanoarchitectonic platforms for supercapatteries
(University of Western cape, 2020)Energy storage technologies are rapidly being developed due to the increased awareness of global warming and growing reliance of society on renewable energy sources. Among various electrochemical energy storage technologies, ... -
Green synthesis of novel nanostructured silicon semiconductor thin film material from sugarcane bagasse ash for solar energy materials
(University of the Western Cape, 2022)The sun is considered the most abundant source of renewable and clean energy. With silicon being the most common element used for the direct conversion of solar energy into electrical energy, solar cells have, over the ... -
Highly selective mesoporous sorbents for mercury removal from industrial wastewater
(University of the Western Cape, 2011)The results of this study show that novel mesoporous carbons were obtained as inverse replica of SBA-15, HMS and MCM-41 silica templates, with a large pore diameter (2-4 nm), a BET surface area of 1867, 874 and 910 m2g–1 ... -
Hydrogel encapsulated biosensors for the detection of biologically significant vanadium and selenium
(University of the Western Cape, 2017)Vanadium and selenium salts are toxic in large amounts, but trace amounts are necessary for cellular function in many organisms. Exposure to high level of selenium has been linked to delays in early childhood development ... -
Identification and quantification of chemicals of emerging concern (persistent organic and inorganic pollutants) in some selected marine environments of cape town, South Africa
(University of the Western Cape, 2020)The increasing evidence of chemicals of emerging concern (CECs) in water bodies is causing major concern around the world because of their toxicological effects upon humans and aquatic organisms. The release of wastewater ... -
Identification, separation and quantification of persistent organic pollutants using capillary electrophoresis
(University of the Western Cape, 2022)Water quality deterioration and scarcity can be attributed to natural causes and anthropogenic activities which include climate change and an incessant industrialisation, yet with lack of functional and reliable wastewater ...