Browsing Philosophiae Doctor - PhD (Chemistry) by Title
Now showing items 93-112 of 133
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Optical and electronic properties of methylammonium lead halide perovskite solar cells
(University of the Western Cape, 2017)Organic-inorganic hybrid perovskite solar cells have emerged as promising materials for next-generation photovoltaics with certified efficiency of 22.1%. Despite rapid developments, achieving precise control over the ... -
Optimisation of biodiesel production via different catalytic and process systems
(University of the Western Cape, 2011)The production of biodiesel (methyl esters) from vegetable oils represents analternative means of producing liquid fuels from biomass, and one which is growing rapidly in commercial importance and relevance due to increase ... -
Palladium surface-modified rare earth metal-based ab5 type hydride-forming materials
(University of the Western Cape, 2008)Driven by mounting standards of living and a growing population, South African energy consumption is expected to increase dramatically within the next decade. The increased demand for more energy will require enormous ... -
Phytochemical and biological studies of extracts from selected South African indigenous medicinal plants: Bulbine and helichrysum species
(University of the Western Cape, 2022)Medicinal plants from the Asteraceae and Asphodelaceae families are among the most widely recognized in South African traditional medicine for managing diabetes mellitus. Diabetes mellitus is a universal epidemic, yet there ... -
Phytochemical studies on extracts of selected South African indigenous medicinal plants
(University of the Western Cape, 2022)Nature has been identified as a rich source of potentially useful chemicals. Throughout the years, phytochemical studies have led to the unearthing of a huge number of natural products, their chemical diversity is unique ... -
Polyamic acid composites for multiiple sensing applications in complex sample matrices
(2013)Polyamic acid-polypyrrole (PAA/PPy) composite films were prepared and characterised for the use as conducting platforms in the design of biosensor systems. The thin films were synthesised by electrochemical method from a ... -
Polymeric-bimetallic oxide nanoalloy for the construction of photovoltaic cells
(University of the Western Cape, 2014)Research in renewable energy has become a focal point as a solution to the energy crisis. One of renewable forms of energy is solar energy, with the main challenge in the development of the solar cells being the high cost. ... -
Preparation and characterization of highly active nano pt/c electrocatalyst for proton exchange membrane fuel cell
(University of the Western Cape, 2006)Catalysts play an essential role in nearly every chemical production process. Platinum supported on high surface area carbon substrates (Pt/C) is one of the promising candidates as an electrocatalyst in low temperature ... -
Preparation and physico-chemical properties of nickel nanostructured materials deposited in etched ion-track membrane
(University of the Western Cape, 2005)The development of finely dispersed powders and superfine-grained materials intended for application in various areas of science and engineering is one of the challenges facing modern nanotechnology. Thus, specific fundamental ... -
Proton conducting polymer composite membrane development for Direct Methanol Fuel Cell applications
(University of Western Cape, 2008)The objective of this study was thus to prepare highly proton condictivity membranes that are cheap to manufacture and have low methanol permeability. -
Pt Nanophase supported catalysts and electrode systems for water electrolysis
(University of the Western Cape, 2008)In this study novel composite electrodes were developed, in which the catalytic components were deposited in nanoparticulate form. The efficiency of the nanophase catalysts and membrane electrodes were tested in an important ... -
Quantum dot sensitized estrogen receptor alpha-recombinant protein electrochemical biosensor for 17-beta estradiol
(University of the Western Cape, 2016)Estrogens play an extraordinary role in the endocrine system regulation through the stimulation and regulation of endocrine pathways. 17β-estradiol is one of the final metabolites in estrogen regulation by hydroxylase ... -
Quantum dots for multiplexed biological imaging
(University of the Western Cape, 2023)Over the past two decades, indium phosphide (InP) colloidal quantum dots (QDs) have attracted substantial interest as a possibly less hazardous alternative to cadmium-based QDs. The improvements in their colloidal synthesis ... -
Quantum dots genosensor for Her2/Neu oncogene - a breast cancer biomarker
(University of the Western Cape, 2014)The human epidermal growth factor receptor (HER)-family of receptor tyrosine kinases; human epidermal growth factor receptor 1, human epidermal growth factor receptor 2, human epidermal growth factor receptor 3 and human ... -
Quantum dots-amplified electrochemical cytochrome P450 phenotype sensor for tamoxifen, a breast cancer drug
(University of the Western Cape, 2017)Breast cancer is regarded as the most common cancer in South Africa and its rate of occurrence is increasing. About one in every 31 South African women are at the risk of developing breast cancer and early diagnosis and ... -
Re-use of South African fly ash for CO2 capture and brine remediation.
(University of the Western Cape, 2013)Coal combustion accounts for 95% of electricity generation in South Africa while globally coal combustion for energy generation stands at 42%. It has been predicted that coal utilization for energy generation will continue ... -
Spectroelectrochemical determination of the antioxidant properties of carpobrotus mellei and carpobrotus quadrifidus natural products
(University of the Western Cape, 2009)South African Carpobrotus species have been found to contain hydrolysable tannins, various tlavonoids e.g. rutin and hyperoside, phytosterols and aromatic acids which have a diverse range of pharmacological properties ... -
Structural investigation of the natural products composition of selected South African seaweeds.
(University of the Western Cape, 2014)Recently, a great deal of interest has developed towards the isolation of bioactive compounds from marine sources due to their numerous health benefits. Furthermore, marine algae are valuable sources ... -
Supercapacitor electrode materials based on nanostructured conducting polymers and metal oxides
(University of the Western Cape, 2013)Supercapacitors are charge-storage devices. Compared to batteries, they have higher power density, more excellent reversibility and longer cycle life. Therefore, supercapacitors have played an increasingly important role ... -
Sustainable synthesis of BEA zeolite from fly ash-based amorphous silica
(University of Western Cape, 2019)Power generation in South Africa depends majorly on the combustion of coal and the increasing demand for energy due to industrialisation and population growth signifies the continuous consumption of coal. During this ...