Browsing Department of Chemistry by Title
Now showing items 130-149 of 399
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Electrochemiluminescence of novel polyanilino-rutheniumbipyridyl-imidazo phenanthroline and carboxy-difluoroboradiazaindacene luminophores
(University of the Western Cape, 2015)Electrochemiluminiscence, (ECL), is an electrochemically-induced process that leads to the generation of measurable luminescent signals at the electrode surface. The luminescent signals occur when electrochemically generated ... -
Electrochemistry and photophysics of carbon nanodots-decorated nigs(Ni(In, Ga)Se2) quantum dots
(university of western cape, 2020)Currently, non-renewable sources are mostly used to meet the ever-growing demand for energy. However, these sources are not sustainable. In addition to these energy sources being not sustainable, they are bad for the ... -
Electrodeposition of multi-valent metal oxides at 1-methyl-3-octylimidazolium bis(trifluoromethylsulfonyl) imide ionic liquid - carbon paste electrode
(University of the Western Cape, 2012)A study on carbon paste electrode (CPE) materials containing 1-methyl-3-octylimidazolium bis (trifluoromethylsulfonyl) imide [MOIM[Tƒ2N] – a hydrophobic room temperature ionic liquid (IL) - is reported. CPEs with (a) the ... -
The electrogeneration of hydroxyl radicals for water disinfection
(University of the Western Cape, 2006)This study has shown that OHË radicals can be generated in an Fe/O2 cell from the electrode products via Fenton’s reaction and used for water disinfection. The cell system in which the experiments were carried out ... -
Electrolytic determination of phthalates organic pollutants with n nostructured titanium and iron oxides sensors
(University of the Western Cape, 2010)This work reports the chemical synthesis, characterisation and electrochemical application of titanium dioxide (TiO2) and iron oxide (Fe2O3) nanoparticles in the determination of phthalates. The other part of this work ... -
Electrospinning of porous composite materials for hydrogen storage application
(University of the Western Cape, 2016)Due to the rapid depletion of fossil fuel reserves and the production of environmentally harmful by-products such as carbon dioxide, there is an urgent need for alternate sustainable clean energy. One of the leading ... -
Encapsulating of humic acid in hydrogel matrix for the complexation of heavy metals in aqueous solutions
(University of Western Cape, 2020)Rapid industrialization growth without appropriate emission standards for discharging environmental pollutants had exposed the ecosystem to detrimental effect. Due to their bioaccumulation propensity in organisms, toxicity ... -
Evaluation of cucurbituril modified screen printed electrodes as efficient host guest agents for small metal cation detection
(University of the Western Cape, 2022)Heavy metals are considered an essential micronutrient and of biological importance for humans and animals. When consumed in adequate amounts supports the body’s immune system by protecting against the effects of free ... -
Evaluation of the leachate chemistry and contaminants attenuation in acid mine drainage by fly ash and its derivatives
(University of the Western Cape, 2006)The mining industry in South Africa has a huge potential to impact negatively on the environment. Negative impacts include generation of reactive tailings and acid mine drainage (AMD). AMD is highly acidic (pH 2-4), ... -
Extraction, fractionation, nanoparticles formulation, and antimicrobial activity of lipids from black soldier fly larvae
(University of Western Cape, 2021)Hermetia illucens (Diptera: Stratiomyidae) known as the black soldier fly (BSF) is an efficient ecological organic waste decomposer. Its larvae grow through six larval instars on a variety of decomposing organic substrates ... -
The extraction, purification and evaluation of compounds from the leaves of Leonotis Leonorus for anticonvulsant activity
(University of the Western Cape, 2002)The aim of this study is to isolate and evaluate the anticonvulsant components from the leaves of Leonotis leonorus (L) R.aR. and to see if there is any change in activity with the origin of the plant material and I or the ... -
Fabrication and kinetic modeling of cytochrome P4502D6 amperometric biosensors for serotonin reuptake inhibitors
(University of the Western Cape, 2005)An amperometric biosensor was prepared by in situ deposition of cytochrome P4502D6 (CYP2D6, P4502D6) enzyme on a polyaniline (PANI)-doped glassy carbon electrode. The PANI film was electrochemically deposited on the electrode ... -
Fabrication of luminescent nanocomposites for diagnosis of breast cancer
(University of the Western Cape, 2016)In this study we were able to synthesize separately iron oxide magnetic nanoparticles, InP/ZnSe and CdTe/ZnS quantum dots. The iron oxide nanoparticles were coupled with InP/ZnSe QDs to form the luminescent magnetic ... -
Fabrication of metal-organic frameworks with application-specific properties for hydrogen storage application
(University of Western Cape, 2019)The application of porous materials into industrial hydrogen (H2) storage systems is based on their use in combination with high-pressure cylinders. The processing of metal-organic frameworks (MOF) powders into shaped ... -
Fabrication of nanomaterials from biomass for adsorption and antimicrobial applications
(University of the Western Cape, 2020)The Black soldier fly (BSF) is an environmentally friendly and sustainable insect utilised in the decomposition of organic waste. This is due to its voracious consumption capability, disruptive functions and economic ... -
Fabrication of type-I indium-based near-infrared emitting quantum dots for biological imaging applications
(University of the Western Cape, 2013)Semiconductor nanocrystals or quantum dots (QDs) are fluorescent nanometer-sized particles which have physical dimensions that are smaller than the excitonic Bohr radius, large surface area-to-volume ratios, broad ... -
Factors influencing fuel cell life and a method of assessment for state of health
(University of the Western Cape, 2018)Proton exchange membrane fuel cells (PEMFC) converts chemical energy from the electrochemical reaction of oxygen and hydrogen into electrical while emitting heat, oxygen depleted air (ODA) and water as by-products. The ... -
The fate and transport of carbon-based nanomaterials in the environment
(University of Western Cape, 2020)The interest in carbon-based nanomaterials, such as carbon-nanodots and graphene, has grown exponentially because these materials have unique properties and applications in the medical, electronic, clean energy and several ... -
Frequency and voltage-modulated electrochemical aflatoxin B1 immunosensor systems prepared on electroactive organic polymer platforms
(University of the Western Cape, 2008)In the presented work, immunosensors for detection of Aflatoxin B1 based on different immobilization platforms were studied. Synthesis of an electroactive hydrogel was also carried out. Aflatoxins are a group of mycotoxins ... -
Frequency and voltage-modulated electrochemical aflatoxin b1immunosensor systems prepared on electroactive organic polymer platforms
(2008)In the presented work, immunosensors for detection of Aflatoxin B1 based on different immobilization platforms were studied. Synthesis of an electroactive hydrogel was also carried out. Aflatoxins are a group of mycotoxins ...