Browsing Department of Chemistry by Title
Now showing items 288-307 of 399
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Polypyrrole supports for direct alcohol fuel cells.
(University of Western Cape, 2021)Anode catalysts are one of the key components of direct alcohol fuel cells (DAFCs). They play a huge role in the alcohol oxidation reaction (AOR) that occurs on the anode side. Palladium (Pd) supported on carbon material ... -
Porous metal complexes for CO2 capturing
(University of the Western Cape, 2017)The need in energy has resulted in the burning of fossil fuels at an increasingly high level. The consequence is a release of high volumes of carbon dioxide gas (CO2) in the atmosphere. This gas is a major greenhouse gas ... -
Preliminary investigation of the natural contamination of agricultural crops with selected mycotoxins in northern rural South Africa (Limpopo and Mpumalanga Provinces)
(University of Western Cape, 2013)Subsistence farmers may contribute significantly to food production, food security, and employment in South Africa. However poor storage practices and contamination with mycotoxins, particularly fumonisins and aflatoxins ... -
Preparation and characterization of highly active nano pt/c electrocatalyst for proton exchange membrane fuel cell
(University of the Western Cape, 2006)Catalysts play an essential role in nearly every chemical production process. Platinum supported on high surface area carbon substrates (Pt/C) is one of the promising candidates as an electrocatalyst in low temperature ... -
Preparation and electrospinning of chitosan from waste Black Soldier Fly biomass
(University of the Western Cape, 2018)Black soldier flies are important in sustainability because of their ability to voraciously degrade organic waste without constituting a nuisance to the environment. In South Africa, Agriprotein Ltd, a company producing ... -
Preparation and physico-chemical properties of nickel nanostructured materials deposited in etched ion-track membrane
(University of the Western Cape, 2005)The development of finely dispersed powders and superfine-grained materials intended for application in various areas of science and engineering is one of the challenges facing modern nanotechnology. Thus, specific fundamental ... -
The preparation of an immunosensor for the detection of microcystins and nodularins by immobilisation of a labelled antibody onto a polymer modified electrode
(University of the Western Cape, 2011)South African dams and reservoirs are increasingly showing the propensity to support sustained populations of Cyanobacteria (blue green algae). These photosynthetic bacteria occur throughout the world and can rapidly form ... -
The preparation of binuclear and polynuclear methyl complexes of palladium as catalyst precursors in phenylacetylene polymerization
(University of the Western Cape, 2007)This study focused on the development of binuclear and multinuclear catalyst for use in vinylic monomer oligomerization and polymerization. The main objective was to develop new homogeneous catalysts systems with hopefully ... -
Production and evaluation of a TiO2 based 68Ge/68Ga generator
(University of the Western Cape, 2014)68Ge/68Ga generators rely on metal oxide, inorganic and organic sorbents in order to prepare radionuclides useful for clinical applications. The requirements for 68Ge/68Ga generators are that the 68Ga obtained from the ... -
Proton conducting polymer composite membrane development for Direct Methanol Fuel Cell applications
(University of Western Cape, 2008)The objective of this study was thus to prepare highly proton condictivity membranes that are cheap to manufacture and have low methanol permeability. -
Pt Nanophase supported catalysts and electrode systems for water electrolysis
(University of the Western Cape, 2008)In this study novel composite electrodes were developed, in which the catalytic components were deposited in nanoparticulate form. The efficiency of the nanophase catalysts and membrane electrodes were tested in an important ... -
Pyramlyl palladium(Il) complexes as phenylacetylene oligomerization and polymerization catalysts'
(University of the Western Cape, 2004)PyrazoM compounds have been extensively used to prepare metal complexes, but it is only recently that they have been investigated as catalysts for the polymerization of unsaturated hydrocarbons. In catalyzn11g the ... -
Pyrazole and pyrazolyl palladium(II) and platinum(II) complexes: synthesis and in vitro evaluation as anticancer agents
(University of the Western Cape, 2004)The use of metallo-pharmaceuticals, such as the platinum drugs, for cancer treatment illustrates the utility of metal complexes as therapeutic agents. Platinum group metal complexes therefore offer potential as anti-tumour ... -
Pyrazolyl palladium complexes with heterocyclic carbonyl linkers as catalyst precursors for ethylene and phenylacetylene polymerization.
(University of the Western Cape, 2003)The pyrazolyl ligands 2,6-bis(3,5-r2p*azolylcarbonyl)pyridine {r : 'bu (l1), me (l2)),2,6-bis(3-methylpyrazolylcarbonyl)pyridine(l3)'2'6- bis(pyrazolylcarbonyl)pyridine (l4) and 2,5-bis(3,5-rzpyrazolylcarbonyl)thiophene { ... -
Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization
(University of the Western Cape, 2005)The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene. -
Quantum dot sensitized estrogen receptor alpha-recombinant protein electrochemical biosensor for 17-beta estradiol
(University of the Western Cape, 2016)Estrogens play an extraordinary role in the endocrine system regulation through the stimulation and regulation of endocrine pathways. 17β-estradiol is one of the final metabolites in estrogen regulation by hydroxylase ... -
Quantum dots for multiplexed biological imaging
(University of the Western Cape, 2023)Over the past two decades, indium phosphide (InP) colloidal quantum dots (QDs) have attracted substantial interest as a possibly less hazardous alternative to cadmium-based QDs. The improvements in their colloidal synthesis ... -
Quantum dots genosensor for Her2/Neu oncogene - a breast cancer biomarker
(University of the Western Cape, 2014)The human epidermal growth factor receptor (HER)-family of receptor tyrosine kinases; human epidermal growth factor receptor 1, human epidermal growth factor receptor 2, human epidermal growth factor receptor 3 and human ... -
Quantum dots-amplified electrochemical cytochrome P450 phenotype sensor for tamoxifen, a breast cancer drug
(University of the Western Cape, 2017)Breast cancer is regarded as the most common cancer in South Africa and its rate of occurrence is increasing. About one in every 31 South African women are at the risk of developing breast cancer and early diagnosis and ... -
Re-use of South African fly ash for CO2 capture and brine remediation.
(University of the Western Cape, 2013)Coal combustion accounts for 95% of electricity generation in South Africa while globally coal combustion for energy generation stands at 42%. It has been predicted that coal utilization for energy generation will continue ...