Browsing Department of Chemistry by Title
Now showing items 365-384 of 399
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The synthesis of methoxy-2-hydroxy-1,4- naphthoquinones and their reaction with aliphatic aldehydes under basic conditions.
(University of the Western Cape, 2003)Although literature reports on the synthesis of variously substituted 2-hydroxy-1 ,4- naphthoquinones appeared to be reasonable; in our hands difficulty was experienced in duplicating much of the work. In order to address ... -
Synthesis of multi-metallic catalysts for fuel cell applications
(University of the Western Cape, 2008)The direct methanol fuel cell or DMFC is emerging as a promising alternative energy source for many applications. Developed and developing countries, through research, are fast seeking a cheap and stable supply of energy ... -
Synthesis of new biguanide derivatives as potential antidiabetic drugs
(University of the Western Cape, 2022)The main purpose of this study was to synthesize biguanide compounds with potential as antidiabetic drugs. All biguanide compounds possess antidiabetic properties by decreasing the blood glucose level. Hence, we embarked ... -
Synthesis of peptide-loaded chitosan nanoparticles for the treatment of sexually transmitted infections (STI’s)
(University of Western Cape, 2019)Peptides are among the main drugs which attract much attention because of their great potential in treating sexually transmitted diseases and other chronic diseases. There has been a major challenge of delivering these ... -
The synthesis of prodrugs and novel analogues of Beta-sympathomimetic bronchodilators
(University of the Western Cape, 1998)Prodrugs are reversible derivatives of active drugs destined to undergo chemical or enzymatic transformation to the active drug after administration in order that the active drug may subsequently elicit the desired ... -
Synthesis of sulphonated and transition metal oxide doped polymeric nanocomposites for application in design of supercapacitors
(University of the Western Cape, 2011)To meet a fast-growing market demand for next generation portable electronic devices with higher performance and increased device functionalities, efficient electrical energy devices with substantially higher energy, power ... -
The synthesis of the cyclometallated palladium complexes and their applications in olefin oligomerization and in phenylacetylene oligomerization/polymerization
(2007)This thesis reports the synthesis of the imine ligands from Schiff base condensation reaction of aldehyde derivatives and equimolar quantities of aniline derivatives. The imine ligands spectrometry. -
The synthesis of Ventiloquinones J and F
(University of Western Cape, 2002)In chapter 2 the synthesis of ventiloquinone J is described, starting from vanillin, the key intermediate cis-3,4-dihydro-5,7-dimethoxy-10- methoxymethyleneoxy-1,3-dimethyl-1H-naphtho[2.3-c]pyran-6,9-dione was prepared ... -
Synthesis of ZSM-5 zeolite from South African fly ash and its application as solid catalyst
(University of the Western cape, 2016)Zeolites are widely used as environmentally friendly solid catalysts or catalyst supports in the refining and petrochemical industries. ZSM-5 zeolite is composed of a three-dimensional medium pore structure (openings of ... -
Synthesis, characterisation and reactions of ferrocene anchored bis(phosphino) palladium (II) and platinum (II) aryldichalcogenide complexes
(University of the Western Cape, 2000)Reactions of M(dppf)Cl2 (M : Pd, Pt) and Pd(dippf)Cl2 with equimolar amounts of the aryldichalcogen reagents, 1,2-benzenedithiol (1,2-(HS)C6H4(SH) (a)), 3,4-toluenedithiol ((HS)C6H3Me(SH)) (b), 3,6-dichloro 1,2-benzenedithiol ... -
Synthesis, characterization and anticancer effects of quantum dots in neuroblastoma and glioblastoma cell lines
(University of the Western Cape, 2018)Introduction: Nanoparticles (NPs) are gaining increased popularity for cancer treatment, especially the multifunctional nanoparticles like Quantum dots (QDs) which have a wide range of applications in nanotheranostics, ... -
Synthesis, characterization and catalytic application of carbonyl complexes of molybdenum and tungsten in epoxidation of some alkenes
(University of the Western Cape, 2010)In this thesis we describe the synthesis of several carbonyl complexes of molybdenum and tungsten, compounds (Cl-ClO). The compounds Cl- C4 are zero valent carbonyl complexes containing N-base ligands prepared by following ... -
Synthesis, characterization and physicochemical properties of platinum naboparticles on ordered mesoporous carbon
(University of the Western Cape, 2011)In this study SBA-15 mesoporous silica template was synthesized and used as a sacrificial template in the preparation of ordered mesoporous carbon material. A chemical vapour deposition (CVD) technique using LPG or ... -
The synthesis, characterization and reactivity of some mononuclear hydrocarbyl compounds of iron
(University of the Western Cape, 1997)Mononuclear hydrocarbyl compounds of the type LnM(CH2)nCH:CH2 (L"M : Cp*Fe(CO)2 and CpFe(CO)2, n: 2-4,6), Cp(CO)zFe(CH2)nOH (n : 4-6,8) and Cp*(CO)2Fe(CH2)+OH have been synthesized. All these compounds have been l3 fully ... -
Synthesis, characterization, and molecular docking of novel 4-Aminoquinolines and Salicylaldimine complexes: evaluation as antimalarial and antitumor agents
(University of the Western Cape, 2016)Malaria remains a major global health problem and to date, hundreds of thousands of people die as a result of this disease every year. Malaria has been able to adapt and rebound despite various efforts made to combat the ... -
Synthesis, characterization, and study mode of coordination of N,N’- and N,O - (arene)ruthenium II complexes co-ligated by isoniazid: Preparation for antimicrobial studies
(University of the Western Cape, 2018)This thesis reports on the syntheses of complexes of (arene) ruthenium (II) isoniazid Schiff base ligands for antimicrobial studies. Isoniazid Schiff base ligands; isonicotinyl acid (2-hydroxy-5- methyl-benzilidene)-hydrazide ... -
Synthesis, electrodynamics and biosensor applications of novel sulphonated polyaniline nanocomposites
(University of the Western Cape, 2007)The overall aim of this thesis was to prepare nanostructured more processable heteronuclear sulphonated polyanyline nanocomposites with electroconductive properties suitable for applications in biosensors. The sulphonated ... -
Synthesis, optical and morphological characterization of pbse quantum dots for diagnostic studies: a model study
(University of the Western Cape, 2013)In this study PbSe quantum dots (QDs) were successfully synthesized via the organometallic and aqueous routes. Optical characterization was carried out using photoluminescence (PL) spectroscopy, structural and morphological ... -
Synthesis, spectroscopic characterization, and cyclic voltammetry studies for salicylaldehyde schiff base ligands and their copper (ii) salicylaldimine compounds
(University of the Western Cape, 2022)Schiff base compounds are a significant class of ligands in coordination chemistry which have been applied widely as they are precise and versatile towards different metal salts. These compounds could be commonly chelating ... -
Synthetic strategies for denatured cytochrome-c analogues towards analytical reporting of NOx species
(University of the Western Cape, 2019)Nitric oxide (NO) plays a key role as biological messenger in the biological system, however detection and quantification thereof has always posed significant problems. NOx is a principal constituent of air pollutants. ...