Magister Scientiae - MSc (Chemistry)
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Recent Submissions
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The synthesis and characterisation of iron and tungsten organometallic polymers with metal-carbon sigma bonds
(University of the Western Cape, 1997)A variety of olefinic organometallic monomers have been synthesised and polymerised under free-radical conditions. These monomers all contain a vinyl moiety as part of an organic fragment which is bonded via a metal-carbon ... -
The catalytic conversion of methane to methanol and formaldehyde under mild conditions
(University of the Western Cape, 2000)The oxidation of methane to produce methanol and formaldehyde is an important process since methanol is used directly as a fuel or can be converted to valuable products such as other transportable fuels , fuel additives, ... -
Polyphenolic, tannin and chemical compositional changes in leaves of sub-tropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations
(University of the Western Cape, 2002)The effects of elevated atmospheric CO2 concentrations on plant polyphenolic concentration, tannin concentration and chemical composition were investigated in leaves of sub-tropical grass species and fynbos shrubs. The ... -
Electrochemical evaluation of chemically Modified microelectrodes
(2001)Aniline and N-alkylated substituted anilines have been polymerized by chemical and electrochemical methods. The chemically synthesized polymers indicated that N-alkylation improves solubility remarkably in common organic ... -
Green synthesis of silver nanoparticles using honey from the meliponinae stingless bee species and antibacterial studies.
(University of the Western Cape, 2023)Green synthesis of silver nanoparticles (AgNPs) is an environmentally friendly approach for preparing nanoparticles using biological sources as the reducing agent. Apart from using plant extracts, honey, that is used in ... -
Organometallic improvement of some tuberculosis drugs
(University of the Western Cape, 2023)Metal-based drugs are preferred motifs that serve as major pharmacophores in bioactive compounds for a variety of diseases, including as tuberculosis (TB). Heterocyclic, Schiff bases, aliphatic amines and other ligands ... -
ISOLATION AND CHARACTERIZATION OF ANTIMICROBIAL COMPOUNDS FROM GALENIA AFRICANA
(University of the Western Cape, 2001)Galenia africona, commonly known as "kraalbos" or "geelbos" belonging to the family Aizoaceae, is a dominant plant throughout the Namaqualand area. It is an active invader and is especially abundant in disturbed areas ... -
The oxidation of the lower primary alcohols ln a catalytic membrane reactor
(University of the Western Cape, 2000)Methanol and ethanol are important chemical feedstock used in industrial chemistry, since they are the starting materials for the synthesis of various products, including hydrocarbons and mild oxidation products. For ... -
Pyrazolyl palladium complexes with heterocyclic carbonyl linkers as catalyst precursors for ethylene and phenylacetylene polymerization.
(University of the Western Cape, 2003)The pyrazolyl ligands 2,6-bis(3,5-r2p*azolylcarbonyl)pyridine {r : 'bu (l1), me (l2)),2,6-bis(3-methylpyrazolylcarbonyl)pyridine(l3)'2'6- bis(pyrazolylcarbonyl)pyridine (l4) and 2,5-bis(3,5-rzpyrazolylcarbonyl)thiophene { ... -
Titanium compounds and plant growth
(University of the Western Cape, 2001)The effect of titanium compounds on the growth of tomato plants, Lycopersicum esculentum (cultivar Floridade), was studied under greenhouse conditions. Aqueous suspensions (TiO2) and solutions (complexes of titanium (IV) ... -
The synthesis of methoxy-2-hydroxy-1,4- naphthoquinones and their reaction with aliphatic aldehydes under basic conditions.
(University of the Western Cape, 2003)Although literature reports on the synthesis of variously substituted 2-hydroxy-1 ,4- naphthoquinones appeared to be reasonable; in our hands difficulty was experienced in duplicating much of the work. In order to address ... -
Hydrothermal synthesis and optimisation of zeolite Na-Pl from South African coal fly ash
(University of Western Cape, 2009)Millions of tonnes of fly ash are generated worldwide every year to satisfy the large demand for energy. Management of this fly ash has been a concern and various approaches for its beneficial use have been investigated. ... -
Substituted nick el pyrazole and palladiumpyruzolyl complexes as catalyst precursors for ethylene polymeization
(University of the Western Cape, 2003)This study concerns the synthesis of pyrazole and substituted pyrazole nickel complexes of the type [(3,5-R,R',pz)2NiB rz ( Pz : pyrazole; R = R' = cHr (1), tBu (a)l and of the type [(3,5-R,R'pz)aNiBrz R: H, R' : CHr ... -
The synthesis of prodrugs and novel analogues of Beta-sympathomimetic bronchodilators
(University of the Western Cape, 1998)Prodrugs are reversible derivatives of active drugs destined to undergo chemical or enzymatic transformation to the active drug after administration in order that the active drug may subsequently elicit the desired ... -
The synthesis of analogues of the Anti-TB (agent: Diospyrin)
(University of the Western Cape, 2005)Diospyrin, a bisnaphthyl quinone molecule with proven anti-TB activity can be retrosynthetically formulated into two halves. In this work, the analogue chosen to be synthesized was similarly retrosynthesized into two halves. ... -
The development of l-phenylalanine biosensor using boron-doped diamond (bdd) electrode modified with poly aniline-polyvinyl sulphonate composite film
(University of the Western Cape, 2010)The aim of this project was to develop a biosensor on a modified boron-doped diamond (BDD) platform in order to determine L-phenylalanine (L-Phe) levels in the aqueous media and real samples. A BDD electrode modified ... -
The synthesis, characterization and reactivity of some mononuclear hydrocarbyl compounds of iron
(University of the Western Cape, 1997)Mononuclear hydrocarbyl compounds of the type LnM(CH2)nCH:CH2 (L"M : Cp*Fe(CO)2 and CpFe(CO)2, n: 2-4,6), Cp(CO)zFe(CH2)nOH (n : 4-6,8) and Cp*(CO)2Fe(CH2)+OH have been synthesized. All these compounds have been l3 fully ... -
Pyramlyl palladium(Il) complexes as phenylacetylene oligomerization and polymerization catalysts'
(University of the Western Cape, 2004)PyrazoM compounds have been extensively used to prepare metal complexes, but it is only recently that they have been investigated as catalysts for the polymerization of unsaturated hydrocarbons. In catalyzn11g the ... -
Synthesis, characterisation and reactions of ferrocene anchored bis(phosphino) palladium (II) and platinum (II) aryldichalcogenide complexes
(University of the Western Cape, 2000)Reactions of M(dppf)Cl2 (M : Pd, Pt) and Pd(dippf)Cl2 with equimolar amounts of the aryldichalcogen reagents, 1,2-benzenedithiol (1,2-(HS)C6H4(SH) (a)), 3,4-toluenedithiol ((HS)C6H3Me(SH)) (b), 3,6-dichloro 1,2-benzenedithiol ... -
Phytochemical synthesis and antimicrobial application of gold nanoparticles from extract of Artemisia annua
(University of the Western Cape, 2023)Metallic nanoparticles synthesized using chemical methods and physical methods are considered toxic to the environment due to the use of toxic solvents. The biological synthesis methods such as the use of plant extracts ...
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