Browsing Magister Scientiae - MSc (Chemistry) by Issue Date
Now showing items 1-20 of 232
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Oxidative fixation of dinitrogen by photocatalysis
(University of Western Cape, 2000)The heterogeneous photocatalytic oxidation of dinitrogen to nitrate, NO3 and/or nitrite, no2 using peroxy species of titanium (IV) in aqueous suspensions has been investigated. The photocatalysts used were titanium peroxide ... -
An investigation into the elements influencing stock control and their relation to health care delivery in the public setting: Development of a stock control assessment tool
(University of the Western Cape, 2000)The aim of this study was to develop a Stock Control Assessment Tool for use in the public health care sector and then to apply it to identify problems in the stock control system. This would help authorities to optimize ... -
The extraction, purification and evaluation of compounds from the leaves of Leonotis Leonorus for anticonvulsant activity
(University of the Western Cape, 2002)The aim of this study is to isolate and evaluate the anticonvulsant components from the leaves of Leonotis leonorus (L) R.aR. and to see if there is any change in activity with the origin of the plant material and I or the ... -
Cesium hydrogen sulphate and cesium dihydrogen phosphate based solid composite electrolyte for fuel cell application
(University of the Western Cape, 2004)A new high temperature solid electrolyte composite was developed, with CsHSO4 and CsH2PO4 as the proton conducting material in composition with PTFE and SiO2 to enhance the solid electrolyte composites mechanical strength ... -
Pyrazole and pyrazolyl palladium(II) and platinum(II) complexes: synthesis and in vitro evaluation as anticancer agents
(University of the Western Cape, 2004)The use of metallo-pharmaceuticals, such as the platinum drugs, for cancer treatment illustrates the utility of metal complexes as therapeutic agents. Platinum group metal complexes therefore offer potential as anti-tumour ... -
Heterocycle carbonyl pyrazolyl palladium(II) complexes :synthesis, ethylene oligomerisation and polymerisation catalysis
(University of the Western Cape, 2004)Reactions of furan, thiophene and alkyl carbonyl chlorides with Unsubstituted and substituted pyrazoles produced the desired pyrazolyl ligands, [R2pyrazole-CO-R/] (R= H, Me, tBu, Ph, R/ = furan, thiophene, Me or tBu) in ... -
Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization
(University of the Western Cape, 2005)The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene. -
Synthesis and characterisation of proton conducting membranes for direct methanol fuel cell (DMFC) applications
(University of the Western Cape, 2005)For a direct methanol fuel cell (DMFC), the proton exchange membrane must conduct protons and be a good methanol barrier. In addition to the high methanol permeability achieved by these membranes, they are very expensive ... -
Synthesis and electrochemical characterisation of conducting polyaniline-fly ash matrix composites
(2005)The aim of this study was to produce useful composite materials from fly ash, a major waste product of coal combustion from power plants. Polyaniline-fly ash (PANI-FA) composites were prepared by in situ polymerisation of ... -
Studies on some biologically active natural products from Tulbaghia Alliacea
(University of the Western Cape, 2005)It is believed that early humans had knowledge of how to use traditional medicinal plants, but the knowledge has been partially lost as society underwent various changes leading to new civilizations. The aim of this study ... -
The Development of Appropriate Brine Electrolysers for Disinfection of Rural water supplies
(University of the Western Cape, 2005)A comparative study of electrolysers using different anodic materials for the electrolysis of brine (sodium chloride) for the production of sodium hypochlorite as a source of A comparative study of electrolysers using ... -
Fabrication and kinetic modeling of cytochrome P4502D6 amperometric biosensors for serotonin reuptake inhibitors
(University of the Western Cape, 2005)An amperometric biosensor was prepared by in situ deposition of cytochrome P4502D6 (CYP2D6, P4502D6) enzyme on a polyaniline (PANI)-doped glassy carbon electrode. The PANI film was electrochemically deposited on the electrode ... -
The application of high capacity ion exchange absorbent material, synthesized from fly ash and acid mine drainage, for the removal of heavy and trace metals from secondary co-disposed process waters
(University of the Western Cape, 2005)The objective of this study was to investigate the feasibility of the application of low cost high capacity inorganic ion exchange material, synthesized form collected fly ash and acid mine drainage solid residues, for the ... -
Polymer/nano-organic composite proton exchange membranes for direct methanol fuel cell application
(University of the Western Cape, 2005)The proton exchange membrane is one key component of direct methanol fuel cells, which has double functions of conducting protons, separating fuels and oxidant. At present, the performance and price of sulfonic acid proton ... -
Characterization of platinum-group metal nanophase electrocatalysts employed in the direct methanol fuel cell and solid-polymer electrolyte electrolyser
(University of the Western Cape, 2005)Characterization of nanophase electrocatalysts, which are an essential part in the direct methanol fuel cell (DMFC) and solid-polymer electrolyte (SPE) electrolyser, have been studied in this work. Their nanoparticulate ... -
The synthesis of 3-allyl-4-ethyl-2- (1'-hydroxyethyl)-1-methoxynaphthalene and its behaviour towards base- and palladium-promoted cyclisation under aerobic and anaerobic conditions
(University of the Western Cape, 2005)Over the years, Giles and co-workers have established that, upon treatment with potassium tert-butoxide, tetra-substituted naphthalenes undergo cyclisations to afford naphthopyrans. It was suggested that these base-induced ... -
The development of appropriate brine electrolysers for disinfection of rural water supplies
(University of the Western Cape, 2005)A comparative study of electrolysers using different anodic materials for the electrolysis of brine (sodium chloride) for the production of sodium hypochlorite as a source of available chlorine for disinfection of rural ... -
Hydrogen selective properties of cesium-hydrogensulphate membranes
(University of the Western Cape, 2006)The production procedure of a CsHS04-Si02 composite membrane was optimized in order to obtain the highest possible H2:C02 and H2:C~ Idea selectivity permeance. The optimized membrane preparation procedure led to the ... -
Homogeneity of nanophase electrocatalysts supported on mesoporous materials
(University of the Western Cape, 2006) -
Phytochemical studies of Helichrysum patulum
(University of the Western Cape, 2006)Since Helichrysum is known by the indigenous people of Africa for therapeutic properties, such as against colds, flu and wounds, the aim of this study was to focus on the patulum species found predominantly in the Western ...
