Browsing Philosophiae Doctor - PhD (Chemistry) by Title
Now showing items 67-86 of 135
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Identification and quantification of chemicals of emerging concern (persistent organic and inorganic pollutants) in some selected marine environments of cape town, South Africa
(University of the Western Cape, 2020)The increasing evidence of chemicals of emerging concern (CECs) in water bodies is causing major concern around the world because of their toxicological effects upon humans and aquatic organisms. The release of wastewater ... -
Identification, separation and quantification of persistent organic pollutants using capillary electrophoresis
(University of the Western Cape, 2022)Water quality deterioration and scarcity can be attributed to natural causes and anthropogenic activities which include climate change and an incessant industrialisation, yet with lack of functional and reliable wastewater ... -
Immunosensors developed on clathrate platform compounds
(University of the Western Cape, 2013)Organic noncyclic compounds were used in the development of immunosensor for rapid fish species detection. Flourene derivatives show unique chemical and physical properties because they contain a rigid planar biphenyl unit, ... -
Impedimetric and electrode kinetic dynamics of DNA aptamer nanobiosensors for estrogeneous endocrine disruptors
(University of the Western Cape, 2011)In this work, DNA aptamer biosensor systems were developed for the detection of l7p-estradiol - an estrogeneous endocrine disrupting chemical (EDC). Endocrine disrupting chemicals are group of compounds that impact negatively ... -
An investigation into the synthesis, characterisation and some applications of novel metal-containing polymers and dendrimers of transition metals
(University of the Western Cape, 2003)metal-containing complexes, that exhibit enhanced chemical and physical properties. This thesis describes the synthesis of new metal-containing linear polymers and dendritic molecules. Chapter 1 presents an overview of ... -
Investigation of anti-cancer potential of Pleiocarpa pycnantha leaves
(University of the Western Cape, 2013)The Apocynaceae family is well known for its potential anticancer activity. Pleiocarpamine isolated from the Apocynaceae family and a constituent of Pleiocarpa pycnantha has been reported for anti-cancer activity. Prompted ... -
Investigation of ternary catalysts as anode catalysts for direct methanol fuel cell
(University of the Western Cape, 2023)This chapter reports on various catalyst synthesis methods (impregnation, polyol, modified polyol and microwave-assisted modified polyol methods) to determine which method would result in the most electrochemically active ... -
Ionophoric and aptameric recognition-modulated electroactive polyaniline films for the determination of tetrodotoxin
(University of the Western Cape, 2014)Tetrodotoxin (TTX) is a nonpeptidic neurotoxin with a high rate of food poisoning mortality (60%) that has been associated with the consumption of diets from puffer fish and mud snails harbouring TTX-producing bacteria. ... -
Isolation and characterization of natural products from selected Rhus species
(University of Western Cape, 2020)Searsia is the more recent name for the genus (Rhus) that contains over 250 individual species of flowering plants in the family Anacardiaceae. Research conducted on Searsia extracts to date indicates a promising potential ... -
Mercaptobenzothiazole-on-Gold Biosensor Systems for Organophosphate and Carbamate Pesticide Compounds
(University of the Western Cape, 2007)This study firstly reports the development, characterisation, and application of thick-film acetylcholinesterase (AChE) biosensors based on a gold electrode modified with a mercaptobenzothiazole (MBT) self-assembled monolayer ... -
Metallic nanoparticles with polymeric shell: A multifunctional platform for application to biosensor
(University of the Western Cape, 2018)Tuberculosis (TB) is an airborne disease caused by Mycobacterium tuberculosis (MTB) that usually affects the lungs leading to severe coughing, fever and chest pains. It was estimated that over 9.6 million people worldwide ... -
Method development for selective recovery of rare earths elements from phosphogypsum waste
(University of Western Cape, 2021)The need for rare earth elements (REEs) in current technologies has motivated countries with high imports dependency to search for alternatives sources. Several studies have been carried out to investigate the feasibility ... -
Microfluidic graphenised-paper electroanalytical devices (μGPED) for adsorptive cathodic stripping voltammetric detection of metal contaminants
(University of the Western Cape, 2017)The need for clean, non-toxic drinking water supplies, free of pollutants and metal contamination is vital in impoverished areas and the developing world alike. With this in mind, the development of accurate, inexpensive, ... -
Microwave synthesized ruthenium antimony oxide-graphene nanocomposite materials for asymmetric supercapacitors
(University of the Western Cape, 2022)With the rapid rise in energy demand and ever-escalating environmental hazards, the need for transition from fossil fuel to renewable energy sources is of paramount importance, requiring better and efficient energy storage ... -
Modification of nanostructured carbon based supports for direct methanol fuel cells
(University of the Western Cape, 2022)Palladium (Pd) and Palladium-Ruthenium (Pd-Ru) nanoparticles supported by various carbon nanomaterials which include graphene oxide (GO), reduced graphene oxide (rGO) and multiwalled carbon nanotubes (MWCNTs) with their ... -
Molecularly imprinted polymer sensor systems for environmental estrogenic endocrine disrupting chemicals
(University of the Western Cape, 2018)There is growing concern on endocrine disrupting compounds (EDCs). The presence of drugs in water supplies was first realized in Germany in the early 1990s when environmental scientists discovered clofibric acid. Clofibric ... -
Mononuclear and multinuclear salicylaldimine metal complexes as catalysts precursors in the oxidation of phenol and cyclohexene
(2009)In this thesis typical homogeneous and dendritic immobilized catalysts derived from salicylaldimines were investigated as catalysts for the oxidation of hydrocarbons using hydrogen peroxide as oxidant under aerobic ... -
Nanoparticulate of silver-modified poly (8-anilino-1-naphthalene sulphonic acid) nanobiosensor systems for the determination of Tuberculosis treatment drugs
(University of the Western Cape, 2011)This study firstly reports the development and characterization of PVP-AgNPs, PANSA and PVPAgNPs/ PANSA nanocomposite on gold. AFM and TEM analyses revealed highly electroactive nanocomposites whose morphogy and properties ... -
Nanostructured light weight hydrogen storage materials
(University of the Western Cape, 2012)The main objective of this study was to advance kinetic performances of formation and decomposition of magnesium hydride by design strategies which include high energy ball milling in hydrogen (HRBM), in combination with ... -
Nanostructured polyamic acid electrocatalysts for reliable analytical reporting of sulphonamides as contaminants of emerging concern
(University of the Western Cape, 2019)Polyamic acid (PAA) nanostructured materials were successfully produced by electrochemical deposition and electrospinning using polyvinlypyrrolidone (PVP) as supporting polymer. Polyamic acid thin film and nanofibers were ...