Department of Chemistry
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Microfluidic graphenised-paper electroanalytical devices (μGPED) for adsorptive cathodic stripping voltammetric detection of metal contaminants
(University of the Western Cape, 2017)The need for clean, non-toxic drinking water supplies, free of pollutants and metal contamination is vital in impoverished areas and the developing world alike. With this in mind, the development of accurate, inexpensive, ... -
Electrochemical poly(ProDOT) dendritic DNA aptamer biosensor for signalling interferon gamma (IFN-ɣ) TB biomarker
(University of the Western Cape, 2017)Tuberculosis (TB) is an infectious disease that, despite all efforts devoted towards its eradication, remains a threat to many countries including South Africa. Current diagnostic assays do offer better performance than ... -
Development of Schiff base electrochemical sensors for the evaluation of polycyclic aromatic hydrocarbons in aqueous medium
(University of the Western Cape, 2017)A novel monomer (N,N'-Bis-(1H-pyrrol-2-ylmethylene)-benzene-1,2-diamine-BPPD) was derived from the condensation reaction between o-phenylenediamine and a pyrrole derivative. The monomer was polymerized electrochemically ... -
Quantum dots-amplified electrochemical cytochrome P450 phenotype sensor for tamoxifen, a breast cancer drug
(University of the Western Cape, 2017)Breast cancer is regarded as the most common cancer in South Africa and its rate of occurrence is increasing. About one in every 31 South African women are at the risk of developing breast cancer and early diagnosis and ... -
The development of graphene oxide sheet- and polyanilino-immunosensor systems for lipoarabinomannan (LAM) tuberculosis biomarker
(University of the Western Cape, 2017)Tuberculosis (TB) is an infectious disease with adverse effect on a global scale. The disease is one of the major causes of death in sub-Saharan Africa. Nearly 70% of TB-infected persons are co-infected by the human ... -
Electrochemical in-situ polymerization of graphene oxide/conducting star copolymer nanocomposite as supercapacitor electrode
(University of the Western Cape, 2017)These days there are deep concerns over the environmental consequences of the rate of consumption of energy from non-renewable sources because of the accelerated increase in greenhouse effect. There is, therefore, increasing ... -
Detection of selective tyrosinase inhibitors from some South African plant extracts of lamiaceae family
(University of the Western Cape, 2016)Various dermatological disorders, such as formation of black pigmented patches on the surface of the skin arise from the over-activity of tyrosinase enzyme's degenerative action. This enzyme is further implicated in the ... -
Synthesis of ZSM-5 zeolite from South African fly ash and its application as solid catalyst
(University of the Western cape, 2016)Zeolites are widely used as environmentally friendly solid catalysts or catalyst supports in the refining and petrochemical industries. ZSM-5 zeolite is composed of a three-dimensional medium pore structure (openings of ... -
Synthesis of sulphonated and transition metal oxide doped polymeric nanocomposites for application in design of supercapacitors
(University of the Western Cape, 2011)To meet a fast-growing market demand for next generation portable electronic devices with higher performance and increased device functionalities, efficient electrical energy devices with substantially higher energy, power ... -
Chemical, physical and morphological changes in weathered brine slurried coal fly ash
(University of the Western Cape, 2011)Energy production from coal comes with an environmental cost because of the toxic waste produced during coal combustion such as coal ash and brine which are potential water and soil pollutants. Coal ash and brine contain ... -
Sorption properties of natural zeolites for the removal of ammonium and chromium ions in aqueous solution
(University of the Western Cape, 2011)There are huge amount of natural clinoptilolite available in South Africa which can be utilised for wastewater treatment of ammonia and chromium if their characteristics are properly known. However, these deposits have not ... -
Electrochemical kinetics and sensing of conjugated dienes in acetonitrile
(University of the Western Cape, 2011)This thesis focuses on the electroanalysis of some dienes (2-methyl-1.3-butadiene (MBD), tran-1.3-pentadiene (PD), 1.3-cyclohexadiene (CHD) and 3-cyclooctadiene (COD)) found in gasoline and the development of simple ... -
Electrochemiluminescence and organic electronics of derivatised poly(aniline sulphonic acid) light-emitting diodes
(University of the Western Cape, 2011)Applications of electrochemiluminescent conjugated polymers offer promising solutions in addressing the problem of light emitting devices. However, the challenging problems that hamper their application in light emitting ... -
Chemical, physical and morphological changes in weathered coal fly ash : a case study of brine impacted wet ash dump
(University of the Western Cape, 2011)Fly ash is the major waste material produced by power plants in the combustion of coal to generate electricity. The main constituents of fly ash are Si, Al, Fe and Ca with smaller amount of S, Mn, Na, K, and traces of ... -
Advanced Ti – based AB and AB2 hydride forming materials
(University of the Western Cape, 2011)Ti – based AB and AB₂ hydride forming materials have shown to be very promising hydrogen storage alloys due to their reasonable reversible hydrogen storage capacity at near ambient conditions, abundance and low cost. ... -
Determination of Chromium(VI), Vanadium(V), Selenium(IV) and Zinc(II) in the City of Cape Town's potable water by stripping voltammetry at boron doped diamond electrodes
(University of the Western Cape, 2011)The main aim of this study is to investigate theelectrochemical determination of two beneficial (selenium and zinc) and two toxic (chromium and vanadium) metals in the potable water within the City of Cape Town's ... -
Durability studies of membrane electrode assemblies for high temperature polymer electrolyte membrane fuel cells
(University of the Western Cape, 2011)Polymer electrolyte membrane fuel cells (PEMFCs) among other fuel cells are considered the best candidate for commercialization of portable and transportation applications because of their high energy conversion and low ... -
Quantum dot sensitized estrogen receptor alpha-recombinant protein electrochemical biosensor for 17-beta estradiol
(University of the Western Cape, 2016)Estrogens play an extraordinary role in the endocrine system regulation through the stimulation and regulation of endocrine pathways. 17β-estradiol is one of the final metabolites in estrogen regulation by hydroxylase ... -
Polyacrylic acid and polyvinylpyrrolidone stabilised ternary nanoalloys of platinum group metals for the electrochemical production of hydrogen from ammonia
(University of the Western Cape, 2016)The electrochemical oxidation of ammonia has attracted much attention as an efficient green method for application in direct ammonia fuel cells (DAFCs) and the production of high purity hydrogen. However, the insufficient ... -
The role of aluminium content in the control of the morphology of fly ash based hierarchical zeolite X
(University of the Western Cape, 2015)Coal is the main source of electricity in South Africa, the combustion of which produces a large amount of waste (coal fly ash) annually. The large-scale generation of coal fly ash places major strain on landfills and the ...
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