Department of Chemistry
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Chemical compositions and leaching behaviour of some South African fly ashe
(University of the Western Cape, 2008)Fly ash is the most abundant of the waste materials generated from coal combustion in coal-fired power stations. South Africa uses more than 100 million tonnes of low grade bituminous coal annually to produce cheap electricity ... -
Electrochemical responses of novel preferentially oriented platinum (100) nanoalloys for ammonia and hydrazine catalysis
(University of the Western Cape, 2013)Ammonia has attracted attention as a possible fuel for direct fuel cells since it is easy to handle under low pressure, costs only slightly higher than methanol and can easily be cracked down into hydrogen and nitrogen. ... -
Electrochemiluminescence of novel polyanilino-rutheniumbipyridyl-imidazo phenanthroline and carboxy-difluoroboradiazaindacene luminophores
(University of the Western Cape, 2015)Electrochemiluminiscence, (ECL), is an electrochemically-induced process that leads to the generation of measurable luminescent signals at the electrode surface. The luminescent signals occur when electrochemically generated ... -
An investigation into the elements influencing stock control and their relation to health care delivery in the public setting: Development of a stock control assessment tool
(University of the Western Cape, 2000)The aim of this study was to develop a Stock Control Assessment Tool for use in the public health care sector and then to apply it to identify problems in the stock control system. This would help authorities to optimize ... -
Re-use of South African fly ash for CO2 capture and brine remediation.
(University of the Western Cape, 2013)Coal combustion accounts for 95% of electricity generation in South Africa while globally coal combustion for energy generation stands at 42%. It has been predicted that coal utilization for energy generation will continue ... -
Impedimetric and electrode kinetic dynamics of DNA aptamer nanobiosensors for estrogeneous endocrine disruptors
(University of the Western Cape, 2011)In this work, DNA aptamer biosensor systems were developed for the detection of l7p-estradiol - an estrogeneous endocrine disrupting chemical (EDC). Endocrine disrupting chemicals are group of compounds that impact negatively ... -
Electro chemiluminescence and organic electronics of derivatised poly(aniline sulphonic acid) light-emitting diodes
(University of the Western Cape, 2011)Electrochemiluminescence (EeL) is applied for industrial applications that have considerable potential, such as clinical diagnostic, analytical chemistry, and light-emitting devices, due to selectivity, sensitivity for ... -
Development of heterostructured tin oxide nanocatalysts for the synthesis of bio-based maleic acid
(University of Western Cape, 2021)Maleic acid (MA) is a key intermediate for the synthesis of polyester resins, surface coatings, lubricant additives, plasticizers, copolymers, pharmaceuticals and agricultural chemicals. The current industrial production ... -
Spectroelectrochemical determination of the antioxidant properties of carpobrotus mellei and carpobrotus quadrifidus natural products
(University of the Western Cape, 2009)South African Carpobrotus species have been found to contain hydrolysable tannins, various tlavonoids e.g. rutin and hyperoside, phytosterols and aromatic acids which have a diverse range of pharmacological properties ... -
Metal modified mesoporous ZSM-5 as catalysts for the oligomerization of 1- hexene
(University of Western Cape, 2021)The use of diesel engines in vehicles and heavy machinery throughout the world has been slowly increasing in the past few decades. This has led to high demand for diesel and gasoline with high octane number. Diesel and ... -
Hydrothermal synthesis of hierarchical ZSM-5 with different Si/Al ratio and their evaluation as catalysts in the catalytic cracking of hexane
(University of Western Cape, 2021)Ethylene and propylene are greatly used for their importance as feedstocks for producing useful materials. Due to rise in prices and the demand of ethylene and propylene, the need to increase the selective production of ... -
Fabrication of type-I indium-based near-infrared emitting quantum dots for biological imaging applications
(University of the Western Cape, 2013)Semiconductor nanocrystals or quantum dots (QDs) are fluorescent nanometer-sized particles which have physical dimensions that are smaller than the excitonic Bohr radius, large surface area-to-volume ratios, broad ... -
Optical and microarray silver-gold based sensors for the detection of e.coli 0157:h7 in seawater
(University of the Western Cape, 2021)Recently researchers reported that nanoparticles functionalised through chemical methods possess risks to the environment and to the human health since they use hazardous chemicals and produce toxic waste. The increasing ... -
Photovoltaic and gas sensing applications of transitional metal nanocomposites of poly(3-hexylthiophene)-titanium dioxide
(University of Western Cape, 2021)This thesis starts with the reviewing of studies on the loading of noble metals and nanostructured metal oxides into bulk heterojunction organic solar cell device architectures. The reviews focused on the innovative ... -
Synthesis of DMSO based silver nanoparticles for application in wound healing
(University of Western Cape, 2021)Silver nanoparticles (AgNPs) apart from being chemically significant, have shown a lot of health benefits, the most studied being their anti-bacterial and anti-inflammatory properties. These biological properties can be ... -
A modified Adams fusion method for the synthesis of binary metal oxide catalysts for the oxygen evolution reaction
(University of Western Cape, 2020)The majority of the global energy is sourced from conventional fossil fuels. The high demand for energy is accelerating along with the depletion of these fossil fuels. Hence, the shift to renewable energy sources and ... -
Development of a bipolar nickel-iron battery prototype for energy storage
(University of Western Cape, 2021)Energy storage systems represent a viable option to integrate renewable energy sources into the grid network. Multiple energy storage technologies are available such as mechanical, electrical, thermal, and electrochemical ... -
Synthesis, characterization and catalytic application of carbonyl complexes of molybdenum and tungsten in epoxidation of some alkenes
(University of the Western Cape, 2010)In this thesis we describe the synthesis of several carbonyl complexes of molybdenum and tungsten, compounds (Cl-ClO). The compounds Cl- C4 are zero valent carbonyl complexes containing N-base ligands prepared by following ... -
The fate and transport of carbon-based nanomaterials in the environment
(University of Western Cape, 2020)The interest in carbon-based nanomaterials, such as carbon-nanodots and graphene, has grown exponentially because these materials have unique properties and applications in the medical, electronic, clean energy and several ... -
Investigation of the natural products composition from the seaweed ulva capensis
(University of Western Cape, 2019)In modern society, diversity of marine macroalgae has become an inspiration for pharmaceutical companies and researchers because of their numerous health benefits, and a great deal of interest has developed towards the ...
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