Magister Scientiae - MSc (Chemistry)
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Graphenised Lithium Iron Phosphate and Lithium Manganese Silicate Hybrid Cathode Systems for Lithium-Ion Batteries
(University of the Western Cape, 2017)This research was based on the development and characterization of graphenised lithium iron phosphate-lithium manganese silicate (LiFePO4-Li2MnSiO4) hybrid cathode materials for use in Li-ion batteries. Although previous ... -
Silver-coated polyethene terephthalate membrane for detection of pharmaceuticals using surface-enhanced Raman spectroscopy
(University of the Western Cape, 2017)Surface-enhanced Raman spectroscopy (SERS) has emerged as one of the analytical tools for detection of micro pollutants in the aquatic environment. The SERS technique is touted to have fingerprinting capability, specificity, ... -
Development of capacitive deionisation electrodes: optimization of fabrication methods and composition
(University of the Western Cape, 2017)The objective of this research was to optimize the fabrication methods for and compositions of electrodes for the Membrane Capacitive Deionisation (MCDI) system. Two electrode fabrication methods were developed, namely a ... -
Carbon supported aluminium trifluoride nanoparticles functionalized lithium manganese oxide for the development of advanced lithium ion battery system
(University of the Western Cape, 2017)A novel lithium ion (Li-ion) battery cathode material has been investigated for potential mobile technology energy storage applications. I have successfully synthesized Lithium Manganese oxide (LMO), reduced Graphene Oxide ... -
Synthesis of metal modified Mesoporous Zeolites catalysts: application in conversion of Olefins to Valuable liquid products
(University of the Western Cape, 2016)The effects of temperature, synthesis duration and silica source were studied to obtain suitable conditions for our laboratory experiment concerned with the synthesis of MCM-41 catalyst. The transformation of 1-hexene was ... -
Porous metal complexes for CO2 capturing
(University of the Western Cape, 2017)The need in energy has resulted in the burning of fossil fuels at an increasingly high level. The consequence is a release of high volumes of carbon dioxide gas (CO2) in the atmosphere. This gas is a major greenhouse gas ... -
Detection of selective Tyrosinase inhibitors from some South African plant extracts of Lamiaceae family
(University of the Western Cape, 2016)Various dermatological disorders, such as formation of black pigmented patches on the surface of the skin arise from the over-activity of tyrosinase enzyme's degenerative action. This enzyme is further implicated in the ... -
Electrospinning of porous composite materials for hydrogen storage application
(University of the Western Cape, 2016)Due to the rapid depletion of fossil fuel reserves and the production of environmentally harmful by-products such as carbon dioxide, there is an urgent need for alternate sustainable clean energy. One of the leading ... -
Recovery of SiO₂ and Al₂O₃ from coal fly ash
(University of the Western Cape, 2016)Most of the world's energy production is still mainly achieved by the combustion of coal in power stations. Coal fly ash is the inevitable waste product that accumulates to metric ton volumes each year. These vast volumes ... -
Electrochemical in-situ polymerization of graphene oxide/conducting star copolymer nanocomposite as supercapacitor electrode
(University of the Western Cape, 2017)These days there are deep concerns over the environmental consequences of the rate of consumption of energy from non-renewable sources because of the accelerated increase in greenhouse effect. There is, therefore, increasing ... -
Detection of selective tyrosinase inhibitors from some South African plant extracts of lamiaceae family
(University of the Western Cape, 2016)Various dermatological disorders, such as formation of black pigmented patches on the surface of the skin arise from the over-activity of tyrosinase enzyme's degenerative action. This enzyme is further implicated in the ... -
Chemical, physical and morphological changes in weathered brine slurried coal fly ash
(University of the Western Cape, 2011)Energy production from coal comes with an environmental cost because of the toxic waste produced during coal combustion such as coal ash and brine which are potential water and soil pollutants. Coal ash and brine contain ... -
Sorption properties of natural zeolites for the removal of ammonium and chromium ions in aqueous solution
(University of the Western Cape, 2011)There are huge amount of natural clinoptilolite available in South Africa which can be utilised for wastewater treatment of ammonia and chromium if their characteristics are properly known. However, these deposits have not ... -
Electrochemical kinetics and sensing of conjugated dienes in acetonitrile
(University of the Western Cape, 2011)This thesis focuses on the electroanalysis of some dienes (2-methyl-1.3-butadiene (MBD), tran-1.3-pentadiene (PD), 1.3-cyclohexadiene (CHD) and 3-cyclooctadiene (COD)) found in gasoline and the development of simple ... -
Electrochemiluminescence and organic electronics of derivatised poly(aniline sulphonic acid) light-emitting diodes
(University of the Western Cape, 2011)Applications of electrochemiluminescent conjugated polymers offer promising solutions in addressing the problem of light emitting devices. However, the challenging problems that hamper their application in light emitting ... -
Chemical, physical and morphological changes in weathered coal fly ash : a case study of brine impacted wet ash dump
(University of the Western Cape, 2011)Fly ash is the major waste material produced by power plants in the combustion of coal to generate electricity. The main constituents of fly ash are Si, Al, Fe and Ca with smaller amount of S, Mn, Na, K, and traces of ... -
Determination of Chromium(VI), Vanadium(V), Selenium(IV) and Zinc(II) in the City of Cape Town's potable water by stripping voltammetry at boron doped diamond electrodes
(University of the Western Cape, 2011)The main aim of this study is to investigate theelectrochemical determination of two beneficial (selenium and zinc) and two toxic (chromium and vanadium) metals in the potable water within the City of Cape Town's ... -
Durability studies of membrane electrode assemblies for high temperature polymer electrolyte membrane fuel cells
(University of the Western Cape, 2011)Polymer electrolyte membrane fuel cells (PEMFCs) among other fuel cells are considered the best candidate for commercialization of portable and transportation applications because of their high energy conversion and low ... -
Polyacrylic acid and polyvinylpyrrolidone stabilised ternary nanoalloys of platinum group metals for the electrochemical production of hydrogen from ammonia
(University of the Western Cape, 2016)The electrochemical oxidation of ammonia has attracted much attention as an efficient green method for application in direct ammonia fuel cells (DAFCs) and the production of high purity hydrogen. However, the insufficient ... -
The role of aluminium content in the control of the morphology of fly ash based hierarchical zeolite X
(University of the Western Cape, 2015)Coal is the main source of electricity in South Africa, the combustion of which produces a large amount of waste (coal fly ash) annually. The large-scale generation of coal fly ash places major strain on landfills and the ...
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