Department of Chemistry: Recent submissions
Now showing items 61-80 of 399
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Isothermal and non-isothermal comparative study of Zn-sn system using real-time RBS
(2021)Solid-state reactions of bi-metallic systems can be driven or activated by various external stimuli like pressure, energetic photons, energetic charged particles or heat. For an example, high pressure torsion can be ... -
Extraction, fractionation, nanoparticles formulation, and antimicrobial activity of lipids from black soldier fly larvae
(University of Western Cape, 2021)Hermetia illucens (Diptera: Stratiomyidae) known as the black soldier fly (BSF) is an efficient ecological organic waste decomposer. Its larvae grow through six larval instars on a variety of decomposing organic substrates ... -
Active neutralisation and amelioration of acid mine drainage with fly ash
(University of the Western Cape, 2009)Due to the constraints being placed on water resources and a drive for major industries to recycle waste water, improved and cheaper water treatment technologies are being investigated. During mining, pyrite (FeS2), a ... -
Treatment of brines using commercial zeolites and zeolites synthesized from fly ash derivative
(University of the Western Cape, 2008)South Africa is one of the countries that have scarce natural resources that they have to preserve what is available at their disposal. South Africa is also fast becoming one of the countries with major industrial development. ... -
Method development for selective recovery of rare earths elements from phosphogypsum waste
(University of Western Cape, 2021)The need for rare earth elements (REEs) in current technologies has motivated countries with high imports dependency to search for alternatives sources. Several studies have been carried out to investigate the feasibility ... -
The Development of Appropriate Brine Electrolysers for Disinfection of Rural water supplies
(University of the Western Cape, 2005)A comparative study of electrolysers using different anodic materials for the electrolysis of brine (sodium chloride) for the production of sodium hypochlorite as a source of A comparative study of electrolysers using ... -
Characterization and Chemical Speciation Modelling of Saline Effluents at Sasol Synthetic Fuels Complex-Secunda and Tutuka Power Station
(University of the Western Cape, 2009)Chemical speciation and the evaluation of species distribution is the key to understanding the potential of brines to form scale or corrode the water circuit as well as the potential of mobility and release trends of the ... -
Microwave synthesis of the Schiff base metal-ligand complexes with Cu and Ni centres
(University of Western Cape, 2021)Nitric oxide (NO) plays a vital role as a biological messenger in biological systems. However, NO detection and quantification have always posed significant complications. There is, therefore, a need to develop new materials ... -
CO2 sequestration using brine impacted fly ash
(University of the Western Cape, 2009)Coal combustion accounts for over 40 % of the world's energy production and this figure is projected to increase with increasing human population and industrialization. The combustion of coal leads to the generation of ... -
Development of Impedimetric Immunosensor for Fumonisin on Polyanilino-Carbon Nanotubes Doped with Palladium Telluride Nanocrystals
(University of the Western Cape, 2013)Immunosensors are affinity ligand-based biosensor solid-state devices in which the immunochemical reaction is coupled to a transducer. The specificity of the molecular recognition of antigens by antibodies to form a stable ... -
Hydrogen selective properties of cesium-hydrogensulphate membranes
(University of the Western Cape, 2006)The production procedure of a CsHS04-Si02 composite membrane was optimized in order to obtain the highest possible H2:C02 and H2:C~ Idea selectivity permeance. The optimized membrane preparation procedure led to the ... -
Brine treatment using natural adsorbents
(University of the Western Cape, 2011)Studies involving the use of natural clays such as bentonite, montmorillonite and natural zeolite clinoptilolite in water treatment have been reported. Researchers suggested cost effective processes, such as ion-exchange ... -
Removal of sulphates from South African mine water using coal fly ash
(University of the Western Cape, 2009)South African power stations generate large amounts of highly alkaline fly ash (FA). This waste product has a serious impact on the environment. Acid mine drainage (AMD) is another environmental problem associated with ... -
Novel aromatic dendritic-co-poly(3-hexylthiophene) composites for photovoltaic cell application
(University of Western Cape, 2021)Fossil fuels are part of fuels that are formed from natural processes and they are called non-renewable sources of energy. These include natural gas, coal and oil. They have been used for decades to produce energy globally. ... -
Dehydrogenation of alkanes using sulfided metal catalysts
(University of Western Cape, 2021)Light olefins are some of the main raw materials for the petrochemical industry. With the rise in oil prices and increasing demand for olefins, there is an increasing interest in finding cheaper alternatives for processes ... -
Photovoltaics of selenide kesterite doped with nanoscopic iron and cerium oxyselenides
(University of Western Cape, 2021)As the demand for energy is constantly increasing, researchers are looking at various methods of energy production. Following the rise of solar energy becoming a major player, researchers are looking at kesterite materials, ... -
Chemical compositions and leaching behaviour of some South African fly ashe
(University of the Western Cape, 2008)Fly ash is the most abundant of the waste materials generated from coal combustion in coal-fired power stations. South Africa uses more than 100 million tonnes of low grade bituminous coal annually to produce cheap electricity ... -
Electrochemical responses of novel preferentially oriented platinum (100) nanoalloys for ammonia and hydrazine catalysis
(University of the Western Cape, 2013)Ammonia has attracted attention as a possible fuel for direct fuel cells since it is easy to handle under low pressure, costs only slightly higher than methanol and can easily be cracked down into hydrogen and nitrogen. ... -
Electrochemiluminescence of novel polyanilino-rutheniumbipyridyl-imidazo phenanthroline and carboxy-difluoroboradiazaindacene luminophores
(University of the Western Cape, 2015)Electrochemiluminiscence, (ECL), is an electrochemically-induced process that leads to the generation of measurable luminescent signals at the electrode surface. The luminescent signals occur when electrochemically generated ... -
An investigation into the elements influencing stock control and their relation to health care delivery in the public setting: Development of a stock control assessment tool
(University of the Western Cape, 2000)The aim of this study was to develop a Stock Control Assessment Tool for use in the public health care sector and then to apply it to identify problems in the stock control system. This would help authorities to optimize ...